N-Substituted Nipecotic Acids as (S)-SNAP-5114 Analogues with Modified Lipophilic Domains.


Journal

ChemMedChem
ISSN: 1860-7187
Titre abrégé: ChemMedChem
Pays: Germany
ID NLM: 101259013

Informations de publication

Date de publication:
06 05 2020
Historique:
received: 20 12 2019
revised: 26 02 2020
pubmed: 19 3 2020
medline: 21 5 2021
entrez: 19 3 2020
Statut: ppublish

Résumé

Potential mGAT4 inhibitors derived from the lead substance (S)-SNAP-5114 have been synthesized and characterized for their inhibitory potency. Variations from the parent compound included the substitution of one of its aromatic 4-methoxy and 4-methoxyphenyl groups, respectively, with a more polar moiety, including a carboxylic acid, alcohol, nitrile, carboxamide, sulfonamide, aldehyde or ketone function, or amino acid partial structures. Furthermore, it was investigated how the substitution of more than one of the aromatic 4-methoxy groups affects the potency and selectivity of the resulting compounds. Among the synthesized test substances (S)-1-{2-[(4-formylphenyl)bis(4-methoxyphenyl)-methoxy]ethyl}piperidine-3-carboxylic acid, that features a carbaldehyde function in place of one of the aromatic 4-methoxy moieties of (S)-SNAP-5114, was found to have a pIC

Identifiants

pubmed: 32187815
doi: 10.1002/cmdc.201900719
pmc: PMC7317212
doi:

Substances chimiques

Enzyme Inhibitors 0
GABA Uptake Inhibitors 0
Nipecotic Acids 0
MGAT4A protein, human EC 2.4.1.-
N-Acetylglucosaminyltransferases EC 2.4.1.-

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

756-771

Informations de copyright

© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

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Auteurs

Michael C Böck (MC)

Department of Pharmacy - Center for Drug Research, Ludwig-Maximilians-Universität München, Butenandtstraße 5-13, 81377, Munich, Germany.

Georg Höfner (G)

Department of Pharmacy - Center for Drug Research, Ludwig-Maximilians-Universität München, Butenandtstraße 5-13, 81377, Munich, Germany.

Klaus T Wanner (KT)

Department of Pharmacy - Center for Drug Research, Ludwig-Maximilians-Universität München, Butenandtstraße 5-13, 81377, Munich, Germany.

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Classifications MeSH