Enhanced Synthetic Access to Tris-CF
Journal
Organic letters
ISSN: 1523-7052
Titre abrégé: Org Lett
Pays: United States
ID NLM: 100890393
Informations de publication
Date de publication:
17 04 2020
17 04 2020
Historique:
pubmed:
2
4
2020
medline:
30
6
2021
entrez:
2
4
2020
Statut:
ppublish
Résumé
Separate focus on the oligomerization and oxidative cyclization steps required for the synthesis of 5,10,15-tris(trifluoromethyl)corrole revealed [bis(trifluoroacetoxy)iodo]benzene (PIFA) as a superior alternative oxidant. Under optimized conditions, the pure free-base corrole was obtained with a 6-fold increase in chemical yield and an 11-fold rise in isolated material per synthesis. The corresponding gallium(III) and manganese(III) complexes were isolated by adding the appropriate metal salt prior to corrole purification.
Identifiants
pubmed: 32227962
doi: 10.1021/acs.orglett.0c00879
pmc: PMC7187640
mid: NIHMS1583218
doi:
Substances chimiques
Organometallic Compounds
0
Porphyrins
0
corrole
0
Manganese
42Z2K6ZL8P
Gallium
CH46OC8YV4
Types de publication
Journal Article
Research Support, N.I.H., Extramural
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
3119-3122Subventions
Organisme : NIDDK NIH HHS
ID : R01 DK019038
Pays : United States
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