Recycling of organic fraction of municipal solid waste as an innovative precursor for the production of bio-based epoxy monomers.

Anaerobiosis Epoxy Resins Recycling Refuse Disposal Solid Waste
Bio-epoxy monomers Organic wastes valorization UV/ozone exposure

Journal

Waste management (New York, N.Y.)
ISSN: 1879-2456
Titre abrégé: Waste Manag
Pays: United States
ID NLM: 9884362

Informations de publication

Date de publication:
15 May 2020
Historique:
received: 08 02 2020
revised: 01 05 2020
accepted: 04 05 2020
pubmed: 16 5 2020
medline: 4 6 2020
entrez: 16 5 2020
Statut: ppublish

Résumé

This paper reports the preparation of newly synthesized bio-epoxy monomers, suitable for replacing petrochemical-derived epoxy resins. An original green method able to produce epoxy monomers starting from neat carbohydrates, waste flours, and even from the organic fraction of municipal solid waste (OFMSW), was here proposed. Hence, for the first time, the epoxidation of carbohydrates was attained only through the exposition to UV and ozone radiation, without using any organic solvent to carry out the reaction. Besides the innovation in the epoxidation method, this work explored the possibility of valorizing waste materials, by recycling carbohydrate scraps; in particular, the exposition of waste flours and municipal solid waste to UV and ozone and their consequent epoxidation allowed obtaining green precursors for the production of a bio-based epoxy resin. Applicability and suitability of the synthesized compounds for epoxy monomers were investigated by curing experiments with a selected amount of a model cycloaliphatic amine-type hardener, i.e. isophorodiamine (IPDA).

Identifiants

DOI: 10.1016/j.wasman.2020.05.004 PMID: 32413725
pubmed: 32413725
pii: S0956-053X(20)30230-0
doi: 10.1016/j.wasman.2020.05.004
pii:
doi:

Substances chimiques

Epoxy Resins 0
Solid Waste 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

212-221

Informations de copyright

Copyright © 2020 Elsevier Ltd. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

Carola Esposito Corcione (C)

Department of Engineering for Innovation, University of Salento, Lecce 73100, Italy. Electronic address: carola.corcione@unisalento.it.

Francesca Ferrari (F)

Department of Engineering for Innovation, University of Salento, Lecce 73100, Italy. Electronic address: francesca.ferrari@unisalento.it.

Raffaella Striani (R)

Department of Engineering for Innovation, University of Salento, Lecce 73100, Italy. Electronic address: raffaella.striani@unisalento.it.

Paolo Visconti (P)

Department of Engineering for Innovation, University of Salento, Lecce 73100, Italy. Electronic address: paolo.visconti@unisalento.it.

Antonio Greco (A)

Department of Engineering for Innovation, University of Salento, Lecce 73100, Italy. Electronic address: antonio.greco@unisalento.it.

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Classifications MeSH

questionsmedicales.fr › Métabolisme › Anaérobiose › Recycling of organic fraction of municipal...
questionsmedicales.fr › Technologie, industrie et agriculture › Produits manufacturés › Matériaux biomédicaux et dentaires › Polymères › Matières plastiques › Résines synthétiques › Résines époxy › Recycling of organic fraction of municipal...
questionsmedicales.fr › Environnement et santé publique › Santé publique › Amélioration du niveau sanitaire › Génie sanitaire › Recyclage › Recycling of organic fraction of municipal...
questionsmedicales.fr › Environnement et santé publique › Santé publique › Amélioration du niveau sanitaire › Génie sanitaire › Gestion des déchets › Élimination des déchets › Recycling of organic fraction of municipal...
questionsmedicales.fr › Environnement et santé publique › Santé publique › Pollution de l'environnement › Déchets › Déchets solides › Recycling of organic fraction of municipal...