Atmospheric organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) in the Antarctic marginal seas: Distribution, sources and transportation.
Antarctica marginal Seas
Atmosphere
OCPs
PCBs
Journal
Chemosphere
ISSN: 1879-1298
Titre abrégé: Chemosphere
Pays: England
ID NLM: 0320657
Informations de publication
Date de publication:
Nov 2020
Nov 2020
Historique:
received:
09
03
2020
revised:
03
06
2020
accepted:
06
06
2020
pubmed:
17
6
2020
medline:
17
9
2020
entrez:
17
6
2020
Statut:
ppublish
Résumé
From November 2013 to March 2014, air samples were collected in the Antarctic marginal seas during the 30th Chinese Antarctic research expedition. Organochlorine pesticides (OCPs) and polychlorinated biphenyls (PCBs) were analyzed in these samples. The mean concentrations were observed for hexachlorobenzene (HCB) >ΣPCBs >Σhexachlorocyclohexanes(HCHs) >Σdichlorodiphenyltrichloroethane(DDTs)>Σchlordanes. High levels of HCB were found near east Antarctica and in the Ross Sea, reflecting the re-emission of HCB from environmental reservoirs of these regions. Parent DDTs (p,p'- and o,p'-DDT) were rarely detected, suggesting that atmospheric DDT was predominantly influencedby weathered DDT from some secondarysources. However, fresh inputs of DDTs could not be excluded because there were still some samples with high proportions of parent DDTs. HCHs only were detected in the South Indian Ocean (near Australia), andthis result might be related to the intense emissions of HCHs from southern Australia. Ratios of trans-chlordane/cis-chlordanein most samples were lower than that in technical chlordane, reflecting the main influence of weathered chlordane. High levels of ΣPCBs were found in the Ross Sea, suggesting an intense re-emission of PCBs. Furthermore, atmospheric PCBs near the Antarctic Peninsula were also relatively high, this finding might be attributed to the emissions of PCBs from nearby Antarctic research stations. Comparing with the Arctic, transport of OCPs and PCBs towards Antarctica is more difficult. The Antarctic marginal seas would act as both barriers and "buffer zones"during the transportation processes.
Identifiants
pubmed: 32544807
pii: S0045-6535(20)31552-6
doi: 10.1016/j.chemosphere.2020.127359
pii:
doi:
Substances chimiques
Air Pollutants
0
Hydrocarbons, Chlorinated
0
Pesticides
0
Polychlorinated Biphenyls
DFC2HB4I0K
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
127359Informations de copyright
Copyright © 2020 Elsevier Ltd. All rights reserved.
Déclaration de conflit d'intérêts
Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.