Strategy for Designing Selective Lysosomal Acid α-Glucosidase Inhibitors: Binding Orientation and Influence on Selectivity.


Journal

Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009

Informations de publication

Date de publication:
19 Jun 2020
Historique:
received: 27 05 2020
revised: 12 06 2020
accepted: 18 06 2020
entrez: 25 6 2020
pubmed: 25 6 2020
medline: 20 2 2021
Statut: epublish

Résumé

Deoxynojirimycin (DNJ) is the archetypal iminosugar, in which the configuration of the hydroxyl groups in the piperidine ring truly mimic those of d-glucopyranose; DNJ and derivatives have beneficial effects as therapeutic agents, such as anti-diabetic and antiviral agents, and pharmacological chaperones for genetic disorders, because they have been shown to inhibit α-glucosidases from various sources. However, attempts to design a better molecule based solely on structural similarity cannot produce selectivity between α-glucosidases that are localized in multiple organs and tissues, because the differences of each sugar-recognition site are very subtle. In this study, we provide the first example of a design strategy for selective lysosomal acid α-glucosidase (GAA) inhibitors focusing on the alkyl chain storage site. Our design of α-1-

Identifiants

pubmed: 32575625
pii: molecules25122843
doi: 10.3390/molecules25122843
pmc: PMC7357040
pii:
doi:

Substances chimiques

Antiviral Agents 0
Glycoside Hydrolase Inhibitors 0
Imino Sugars 0
deoxynojirimycine 0
1-Deoxynojirimycin 19130-96-2
alpha-Glucosidases EC 3.2.1.20
Glucosamine N08U5BOQ1K

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Subventions

Organisme : Japanese Society for the Promotion of Science
ID : JSPS KAKENHI Grant Number JP17K08362

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Auteurs

Atsushi Kato (A)

Department of Hospital Pharmacy, University of Toyama, Toyama 930-0194, Japan.

Izumi Nakagome (I)

School of Pharmaceutical Sciences, Kitasato University, Tokyo 108-8641, Japan.

Mizuki Hata (M)

Department of Hospital Pharmacy, University of Toyama, Toyama 930-0194, Japan.

Robert J Nash (RJ)

Institute of Biological, Environmental and Rural Sciences, Plas Gogerddan, Aberystwyth, Ceredigion SY23 3EB, UK.

George W J Fleet (GWJ)

Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Oxford OX1 3TA, UK.

Yoshihiro Natori (Y)

Faculty of Pharmaceutical Sciences, Tohoku Pharmaceutical University, Sendai 981-8558, Japan.

Yuichi Yoshimura (Y)

Faculty of Pharmaceutical Sciences, Tohoku Pharmaceutical University, Sendai 981-8558, Japan.

Isao Adachi (I)

Department of Hospital Pharmacy, University of Toyama, Toyama 930-0194, Japan.

Shuichi Hirono (S)

School of Pharmaceutical Sciences, Kitasato University, Tokyo 108-8641, Japan.

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Classifications MeSH