"Dumb" pH-Independent and Biocompatible Hydrogels Formed by Copolymers of Long-Chain Alkyl Glycidyl Ethers and Ethylene Oxide.

Epoxy Compounds Ethylene Oxide Hydrogels Hydrogen-Ion Concentration Kinetics Polyethylene Glycols Polymers

Journal

Biomacromolecules
ISSN: 1526-4602
Titre abrégé: Biomacromolecules
Pays: United States
ID NLM: 100892849

Informations de publication

Date de publication:
10 08 2020
Historique:
pubmed: 1 7 2020
medline: 22 6 2021
entrez: 1 7 2020
Statut: ppublish

Résumé

The formation and rheological properties of hydrogels based on amphiphilic ABA triblock polyether copolymers are described, relying solely on the hydrophobic interaction of long-chain alkyl glycidyl ether (AlkGE)- based A-blocks that are combined with a hydrophilic poly(ethylene glycol) (PEG) midblock. Via anionic ring-opening copolymerization (AROP), ethylene oxide (EO) and long-chain alkyl glycidyl ethers (AlkGEs) were copolymerized, using deprotonated poly(ethylene glycol) (PEG) macroinitiators (

Identifiants

DOI: 10.1021/acs.biomac.0c00576 PMID: 32603096
pubmed: 32603096
doi: 10.1021/acs.biomac.0c00576
doi:

Substances chimiques

ABA triblock copolymers 0
Epoxy Compounds 0
Hydrogels 0
Polymers 0
glycidyl ethers 0
Polyethylene Glycols 3WJQ0SDW1A
Ethylene Oxide JJH7GNN18P

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

3152-3162

Auteurs

Patrick Verkoyen (P)

Department of Chemistry, Johannes Gutenberg University Mainz, Duesbergweg 10-14, 55128 Mainz, Germany.

Philip Dreier (P)

Department of Chemistry, Johannes Gutenberg University Mainz, Duesbergweg 10-14, 55128 Mainz, Germany.

Matthias Bros (M)

Department of Dermatology, University Medical Center of the Johannes Gutenberg University Mainz, Langenbeckstrasse 1, 55131 Mainz, Germany.

Christian Hils (C)

Makromolekulare Chemie II, University of Bayreuth, 95440 Bayreuth, Germany.

Holger Schmalz (H)

Makromolekulare Chemie II, University of Bayreuth, 95440 Bayreuth, Germany.
ORCID: 0000-0002-4876-0450

Sebastian Seiffert (S)

Department of Chemistry, Johannes Gutenberg University Mainz, Duesbergweg 10-14, 55128 Mainz, Germany.
ORCID: 0000-0002-5152-1207

Holger Frey (H)

Department of Chemistry, Johannes Gutenberg University Mainz, Duesbergweg 10-14, 55128 Mainz, Germany.
ORCID: 0000-0002-9916-3103

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Classifications MeSH

questionsmedicales.fr › Composés chimiques organiques › Éthers › Composés époxy › "Dumb" pH-Independent and Biocompatible...
questionsmedicales.fr › Composés chimiques organiques › Éthers › Composés époxy › Oxirane › "Dumb" pH-Independent and Biocompatible...
questionsmedicales.fr › Préparations pharmaceutiques › Colloïdes › Gels › Hydrogels › "Dumb" pH-Independent and Biocompatible...
questionsmedicales.fr › Phénomènes chimiques › Concentration en ions d'hydrogène › "Dumb" pH-Independent and Biocompatible...
questionsmedicales.fr › Phénomènes chimiques › Phénomènes biochimiques › Cinétique › "Dumb" pH-Independent and Biocompatible...
questionsmedicales.fr › Technologie, industrie et agriculture › Produits manufacturés › Matériaux biomédicaux et dentaires › Polymères › Polyéthylène glycols › "Dumb" pH-Independent and Biocompatible...
questionsmedicales.fr › Technologie, industrie et agriculture › Produits manufacturés › Matériaux biomédicaux et dentaires › Polymères › "Dumb" pH-Independent and Biocompatible...