Self-Propelled Supracolloidal Fibers from Multifunctional Polymer Surfactants and Droplets.
Marangoni flow
adhesive emulsions
polymer zwitterions
self-propelled fibers
supracolloidal materials
Journal
Macromolecular rapid communications
ISSN: 1521-3927
Titre abrégé: Macromol Rapid Commun
Pays: Germany
ID NLM: 9888239
Informations de publication
Date de publication:
Aug 2020
Aug 2020
Historique:
received:
22
06
2020
pubmed:
17
7
2020
medline:
28
11
2020
entrez:
17
7
2020
Statut:
ppublish
Résumé
Advanced synthetic materials are needed to produce nano- and mesoscale structures that function autonomously, catalyze reactions, and convert chemical energy into motion. This paper describes supracolloidal fiber-like structures that are composed of self-adhering, or "sticky," oil-in-water emulsion droplets. Polymer zwitterion surfactants serve as the key interfacial components of these materials, enabling multiple functions simultaneously, including acting as droplet-stabilizing surfactants, interdroplet adhesives, and building blocks of the fibers. This fiber motion, a surprising additional feature of these supracolloidal structures, is observed at the air-water interface and hinged on the chemistry of the polymer surfactant. The origin of this motion is hypothesized to involve transport of polymer from the oil-water interface to the air-water interface, which generates a Marangoni (interfacial) stress. Harnessing this fiber motion with functional polymer surfactants, and selection of the oil phase, produced worm-like objects capable of rotation, oscillation, and/or response to external fields. Overall, these supracolloidal fibers fill a design gap between self-propelled nano/microscale particles and macroscale motors, and have the potential to serve as new components of soft, responsive materials structures.
Identifiants
pubmed: 32671939
doi: 10.1002/marc.202000334
doi:
Substances chimiques
Benzopyrans
0
Emulsions
0
Hexanes
0
Indoles
0
Nitro Compounds
0
Polymers
0
Surface-Active Agents
0
merocyanine
0
spiropyran
0
Water
059QF0KO0R
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2000334Subventions
Organisme : National Science Foundation
ID : NSF-CCI-1740630
Informations de copyright
© 2020 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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