A rapid and convenient screening method for detection of restricted monensin, decoquinate, and lasalocid in animal feed by applying SERS and chemometrics.


Journal

Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association
ISSN: 1873-6351
Titre abrégé: Food Chem Toxicol
Pays: England
ID NLM: 8207483

Informations de publication

Date de publication:
Oct 2020
Historique:
received: 04 06 2020
revised: 03 07 2020
accepted: 17 07 2020
pubmed: 2 8 2020
medline: 22 5 2021
entrez: 2 8 2020
Statut: ppublish

Résumé

The surface-enhanced activities of size- and shape-controlled gold nanoparticles (AuNPs) with superior chemical stability were investigated to explore a possible development of a simple and non-destructive spectroscopic method to help the regulatory agency's analytical services for rapid detection and characterization of selected antimicrobials in animal feeds. Feed samples spiked at different concentration ranges of antimicrobials were evaluated using AuNPs as a surface-enhanced Raman spectroscopy (SERS) agent. The collected SERS spectra were mathematically preprocessed for further analysis. The classification models obtained 100% predictive accuracy with zero or little misclassification. The first two canonical variables (p = 0.001) could explain >95% of the variability in preprocessed spectral data. Most chemometric models for predicting MON, DEC, and LAS concentrations showed a high predictive accuracy (r

Identifiants

pubmed: 32738374
pii: S0278-6915(20)30523-8
doi: 10.1016/j.fct.2020.111633
pii:
doi:

Substances chimiques

Anti-Infective Agents 0
Decoquinate 534I52PVWH
Gold 7440-57-5
Monensin 906O0YJ6ZP
Lasalocid W7V2ZZ2FWB

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

111633

Informations de copyright

Published by Elsevier Ltd.

Auteurs

Kyung-Min Lee (KM)

Office of the Texas State Chemist, Texas A&M AgriLife Research, Texas A&M University System, College Station, TX, 77843, United States. Electronic address: kml@otsc.tamu.edu.

Danielle Yarbrough (D)

Department of Chemical Engineering, Texas A&M University, College Station, TX, 77843, United States.

Mena M Kozman (MM)

Department of Biology, Texas A&M University, College Station, TX, 77843, United States.

Timothy J Herrman (TJ)

Office of the Texas State Chemist, Texas A&M AgriLife Research, Texas A&M University System, College Station, TX, 77843, United States.

Jinhyuk Park (J)

Department of Biological and Agricultural Engineering, Texas A&M University, College Station, TX, 77843, United States.

Rui Wang (R)

Department of Biochemistry and Biophysics, Texas A&M University, College Station, TX, 77843, United States.

Dmitry Kurouski (D)

Department of Biochemistry and Biophysics, Texas A&M University, College Station, TX, 77843, United States.

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Classifications MeSH