Hyaluronic Acid-Based Bioink Composition Enabling 3D Bioprinting and Improving Quality of Deposited Cartilaginous Extracellular Matrix.

biofabrication bioinks chondrogenic differentiation extracellular matrix hyaluronic acid

Journal

Advanced healthcare materials
ISSN: 2192-2659
Titre abrégé: Adv Healthc Mater
Pays: Germany
ID NLM: 101581613

Informations de publication

Date de publication:
08 2020
Historique:
received: 01 05 2020
revised: 26 06 2020
entrez: 7 8 2020
pubmed: 7 8 2020
medline: 15 5 2021
Statut: ppublish

Résumé

In 3D bioprinting, bioinks with high concentrations of polymeric materials are frequently used to enable fabrication of 3D cell-hydrogel constructs with sufficient stability. However, this is often associated with restricted cell bioactivity and an inhomogeneous distribution of newly produced extracellular matrix (ECM). Therefore, this study investigates bioink compositions based on hyaluronic acid (HA), an attractive material for cartilage regeneration, which allow for reduction of polymer content. Thiolated HA and allyl-modified poly(glycidol) in varying concentrations are UV-crosslinked. To adapt bioinks to poly(ε-caprolactone) (PCL)-supported 3D bioprinting, the gels are further supplemented with 1 wt% unmodified high molecular weight HA (hmHA) and chondrogenic differentiation of incorporated human mesenchymal stromal cells is assessed. Strikingly, addition of hmHA to gels with a low polymer content (3 wt%) results in distinct increase of construct quality with a homogeneous ECM distribution throughout the constructs, independent of the printing process. Improved ECM distribution in those constructs is associated with increased construct stiffness after chondrogenic differentiation, as compared to higher concentrated constructs (10 wt%), which only show pericellular matrix deposition. The study contributes to effective bioink development, demonstrating dual function of a supplement enabling PCL-supported bioprinting and at the same time improving biological properties of the resulting constructs.

Identifiants

pubmed: 32757263
doi: 10.1002/adhm.202000737
doi:

Substances chimiques

Hyaluronic Acid 9004-61-9

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2000737

Informations de copyright

© 2020 The Authors. Published by Wiley-VCH GmbH.

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Auteurs

Julia Hauptstein (J)

Department of Trauma, Hand, Plastic and Reconstructive Surgery, University of Würzburg, 97080, Würzburg, Germany.

Thomas Böck (T)

Chair for Functional Materials in Medicine and Dentistry and Bavarian Polymer Institute, University of Würzburg, 97070, Würzburg, Germany.

Michael Bartolf-Kopp (M)

Chair for Functional Materials in Medicine and Dentistry and Bavarian Polymer Institute, University of Würzburg, 97070, Würzburg, Germany.

Leonard Forster (L)

Chair for Functional Materials in Medicine and Dentistry and Bavarian Polymer Institute, University of Würzburg, 97070, Würzburg, Germany.

Philipp Stahlhut (P)

Chair for Functional Materials in Medicine and Dentistry and Bavarian Polymer Institute, University of Würzburg, 97070, Würzburg, Germany.

Ali Nadernezhad (A)

Chair for Functional Materials in Medicine and Dentistry and Bavarian Polymer Institute, University of Würzburg, 97070, Würzburg, Germany.

Gina Blahetek (G)

Institute of Experimental Biomedicine II, University Hospital Würzburg, Würzburg, 97080, Germany.

Alma Zernecke-Madsen (A)

Institute of Experimental Biomedicine II, University Hospital Würzburg, Würzburg, 97080, Germany.

Rainer Detsch (R)

Institute of Biomaterials, Department of Materials Science and Engineering, University of Erlangen-Nuremberg, 91058, Erlangen, Germany.

Tomasz Jüngst (T)

Chair for Functional Materials in Medicine and Dentistry and Bavarian Polymer Institute, University of Würzburg, 97070, Würzburg, Germany.

Jürgen Groll (J)

Chair for Functional Materials in Medicine and Dentistry and Bavarian Polymer Institute, University of Würzburg, 97070, Würzburg, Germany.

Jörg Teßmar (J)

Chair for Functional Materials in Medicine and Dentistry and Bavarian Polymer Institute, University of Würzburg, 97070, Würzburg, Germany.

Torsten Blunk (T)

Department of Trauma, Hand, Plastic and Reconstructive Surgery, University of Würzburg, 97080, Würzburg, Germany.

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