Designed CXCR4 mimic acts as a soluble chemokine receptor that blocks atherogenic inflammation by agonist-specific targeting.


Journal

Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555

Informations de publication

Date de publication:
25 11 2020
Historique:
received: 02 12 2019
accepted: 28 10 2020
entrez: 26 11 2020
pubmed: 27 11 2020
medline: 15 12 2020
Statut: epublish

Résumé

Targeting a specific chemokine/receptor axis in atherosclerosis remains challenging. Soluble receptor-based strategies are not established for chemokine receptors due to their discontinuous architecture. Macrophage migration-inhibitory factor (MIF) is an atypical chemokine that promotes atherosclerosis through CXC-motif chemokine receptor-4 (CXCR4). However, CXCR4/CXCL12 interactions also mediate atheroprotection. Here, we show that constrained 31-residue-peptides ('msR4Ms') designed to mimic the CXCR4-binding site to MIF, selectively bind MIF with nanomolar affinity and block MIF/CXCR4 without affecting CXCL12/CXCR4. We identify msR4M-L1, which blocks MIF- but not CXCL12-elicited CXCR4 vascular cell activities. Its potency compares well with established MIF inhibitors, whereas msR4M-L1 does not interfere with cardioprotective MIF/CD74 signaling. In vivo-administered msR4M-L1 enriches in atherosclerotic plaques, blocks arterial leukocyte adhesion, and inhibits atherosclerosis and inflammation in hyperlipidemic Apoe

Identifiants

pubmed: 33239628
doi: 10.1038/s41467-020-19764-z
pii: 10.1038/s41467-020-19764-z
pmc: PMC7689490
doi:

Substances chimiques

Antigens, CD 0
CXCL12 protein, human 0
CXCR4 protein, human 0
Chemokine CXCL12 0
Macrophage Migration-Inhibitory Factors 0
Peptide Fragments 0
Receptors, CXCR4 0
Sialyltransferases EC 2.4.99.-
ST6GAL1 protein, human EC 2.4.99.1
Intramolecular Oxidoreductases EC 5.3.-
MIF protein, human EC 5.3.2.1
Mif protein, mouse EC 5.3.2.1

Types de publication

Journal Article Research Support, N.I.H., Extramural Research Support, Non-U.S. Gov't Video-Audio Media

Langues

eng

Sous-ensembles de citation

IM

Pagination

5981

Subventions

Organisme : NCATS NIH HHS
ID : UL1 TR001863
Pays : United States

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Auteurs

Christos Kontos (C)

Division of Peptide Biochemistry, TUM School of Life Sciences, Technische Universität München (TUM), 85354, Freising, Germany.

Omar El Bounkari (O)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.

Christine Krammer (C)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.

Dzmitry Sinitski (D)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.

Kathleen Hille (K)

Division of Peptide Biochemistry, TUM School of Life Sciences, Technische Universität München (TUM), 85354, Freising, Germany.

Chunfang Zan (C)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.

Guangyao Yan (G)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.

Sijia Wang (S)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.

Ying Gao (Y)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.

Markus Brandhofer (M)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.

Remco T A Megens (RTA)

Institute for Cardiovascular Prevention, Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 80336, Munich, Germany.

Adrian Hoffmann (A)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.
Department of Anaesthesiology, Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.

Jessica Pauli (J)

Department for Vascular and Endovascular Surgery, Klinikum rechts der Isar, Technische Universität München (TUM), 81675, Munich, Germany.

Yaw Asare (Y)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.

Simona Gerra (S)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.

Priscila Bourilhon (P)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.

Lin Leng (L)

Yale University School of Medicine, New Haven, CT, 06510, USA.

Hans-Henning Eckstein (HH)

Department for Vascular and Endovascular Surgery, Klinikum rechts der Isar, Technische Universität München (TUM), 81675, Munich, Germany.

Wolfgang E Kempf (WE)

Department for Vascular and Endovascular Surgery, Klinikum rechts der Isar, Technische Universität München (TUM), 81675, Munich, Germany.

Jaroslav Pelisek (J)

Department for Vascular and Endovascular Surgery, Klinikum rechts der Isar, Technische Universität München (TUM), 81675, Munich, Germany.
Department of Vascular Surgery, University Hospital Zurich, 8091, Zurich, Switzerland.

Ozgun Gokce (O)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.
Munich Cluster for Systems Neurology (SyNergy), 81377, Munich, Germany.

Lars Maegdefessel (L)

Department for Vascular and Endovascular Surgery, Klinikum rechts der Isar, Technische Universität München (TUM), 81675, Munich, Germany.

Richard Bucala (R)

Yale University School of Medicine, New Haven, CT, 06510, USA.

Martin Dichgans (M)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany.
Munich Cluster for Systems Neurology (SyNergy), 81377, Munich, Germany.

Christian Weber (C)

Institute for Cardiovascular Prevention, Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 80336, Munich, Germany.
Munich Cluster for Systems Neurology (SyNergy), 81377, Munich, Germany.
Munich Heart Alliance, 80802, Munich, Germany.
Cardiovascular Research Institute Maastricht (CARIM), Maastricht University, 6229, Maastricht, The Netherlands.

Aphrodite Kapurniotu (A)

Division of Peptide Biochemistry, TUM School of Life Sciences, Technische Universität München (TUM), 85354, Freising, Germany. akapurniotu@wzw.tum.de.

Jürgen Bernhagen (J)

Institute for Stroke and Dementia Research (ISD), Klinikum der Universität München, Ludwig-Maximilians-Universität (LMU) München, 81377, Munich, Germany. juergen.bernhagen@med.uni-muenchen.de.
Munich Cluster for Systems Neurology (SyNergy), 81377, Munich, Germany. juergen.bernhagen@med.uni-muenchen.de.
Munich Heart Alliance, 80802, Munich, Germany. juergen.bernhagen@med.uni-muenchen.de.

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