Enantiomeric Resolution and Absolute Configuration of a Chiral δ-Lactam, Useful Intermediate for the Synthesis of Bioactive Compounds.

X-ray diffraction absolute configuration assignment chiral resolution enantioselective HPLC lactam scaffold

Journal

Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009

Informations de publication

Date de publication:
19 Dec 2020
Historique:
received: 02 12 2020
revised: 15 12 2020
accepted: 18 12 2020
entrez: 23 12 2020
pubmed: 24 12 2020
medline: 10 4 2021
Statut: epublish

Résumé

During the past several years, the frequency of discovery of new molecular entities based on γ- or δ-lactam scaffolds has increased continuously. Most of them are characterized by the presence of at least one chiral center. Herein, we present the preparation, isolation and the absolute configuration assignment of enantiomeric 2-(4-bromophenyl)-1-isobutyl-6-oxopiperidin-3-carboxylic acid (

Identifiants

pubmed: 33352660
pii: molecules25246023
doi: 10.3390/molecules25246023
pmc: PMC7766352
pii:
doi:

Substances chimiques

Biological Factors 0
Lactams 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

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Auteurs

Roberta Listro (R)

Department of Drug Sciences, University of Pavia, via Taramelli 12, 27100 Pavia, Italy.

Giacomo Rossino (G)

Department of Drug Sciences, University of Pavia, via Taramelli 12, 27100 Pavia, Italy.

Serena Della Volpe (S)

Department of Drug Sciences, University of Pavia, via Taramelli 12, 27100 Pavia, Italy.

Rita Stabile (R)

Department of Drug Sciences, University of Pavia, via Taramelli 12, 27100 Pavia, Italy.

Massimo Boiocchi (M)

Centro Grandi Strumenti, University of Pavia, via Bassi 21, 27100 Pavia, Italy.

Lorenzo Malavasi (L)

Department of Chemistry, University of Pavia, via Taramelli 12, 27100 Pavia, Italy.

Daniela Rossi (D)

Department of Drug Sciences, University of Pavia, via Taramelli 12, 27100 Pavia, Italy.

Simona Collina (S)

Department of Drug Sciences, University of Pavia, via Taramelli 12, 27100 Pavia, Italy.

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