Flagellin-based electrochemical sensing layer for arsenic detection in water.


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
10 02 2021
Historique:
received: 25 09 2020
accepted: 27 01 2021
entrez: 11 2 2021
pubmed: 12 2 2021
medline: 16 11 2021
Statut: epublish

Résumé

Regular monitoring of arsenic concentrations in water sources is essential due to the severe health effects. Our goal was to develop a rapidly responding, sensitive and stable sensing layer for the detection of arsenic. We have designed flagellin-based arsenic binding proteins capable of forming stable filament structures with high surface binding site densities. The D3 domain of Salmonella typhimurium flagellin was replaced with an arsenic-binding peptide motif of different bacterial ArsR transcriptional repressor factors. We have shown that the fusion proteins developed retain their polymerization ability and have thermal stability similar to that of wild-type filament. The strong arsenic binding capacity of the monomeric proteins was confirmed by isothermal titration calorimetry (ITC), and dissociation constants (K

Identifiants

pubmed: 33568718
doi: 10.1038/s41598-021-83053-y
pii: 10.1038/s41598-021-83053-y
pmc: PMC7876115
doi:

Substances chimiques

Proteins 0
Water 059QF0KO0R
Flagellin 12777-81-0
Gold 7440-57-5
Arsenic N712M78A8G

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

3497

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Auteurs

Hajnalka Jankovics (H)

Research Institute of Biomolecular and Chemical Engineering, University of Pannonia, P.O. Box 125, Veszprém, 8200, Hungary. jankovicsh@almos.uni-pannon.hu.

Patrik Szekér (P)

Research Institute of Biomolecular and Chemical Engineering, University of Pannonia, P.O. Box 125, Veszprém, 8200, Hungary.

Éva Tóth (É)

Research Institute of Biomolecular and Chemical Engineering, University of Pannonia, P.O. Box 125, Veszprém, 8200, Hungary.

Balázs Kakasi (B)

Research Institute of Biomolecular and Chemical Engineering, University of Pannonia, P.O. Box 125, Veszprém, 8200, Hungary.

Zoltán Lábadi (Z)

Institute of Technical Physics and Materials Science, Centre for Energy Research, P.O. Box 49, Budapest, 1525, Hungary.

András Saftics (A)

Institute of Technical Physics and Materials Science, Centre for Energy Research, P.O. Box 49, Budapest, 1525, Hungary.

Benjamin Kalas (B)

Institute of Technical Physics and Materials Science, Centre for Energy Research, P.O. Box 49, Budapest, 1525, Hungary.

Miklós Fried (M)

Institute of Technical Physics and Materials Science, Centre for Energy Research, P.O. Box 49, Budapest, 1525, Hungary.
Institute of Microelectronics and Technology, Óbuda University, P.O. Box 112, Budapest, 1431, Hungary.

Péter Petrik (P)

Institute of Technical Physics and Materials Science, Centre for Energy Research, P.O. Box 49, Budapest, 1525, Hungary.

Ferenc Vonderviszt (F)

Research Institute of Biomolecular and Chemical Engineering, University of Pannonia, P.O. Box 125, Veszprém, 8200, Hungary.
Institute of Technical Physics and Materials Science, Centre for Energy Research, P.O. Box 49, Budapest, 1525, Hungary.

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Classifications MeSH