Enantioselective Formation of Quaternary Centers by Allylic Alkylation with First-Row Transition-Metal Catalysts.
Journal
Chemical reviews
ISSN: 1520-6890
Titre abrégé: Chem Rev
Pays: United States
ID NLM: 2985134R
Informations de publication
Date de publication:
14 04 2021
14 04 2021
Historique:
pubmed:
12
2
2021
medline:
28
9
2021
entrez:
11
2
2021
Statut:
ppublish
Résumé
Asymmetric allylic alkylation mediated by transition metals provides an efficient strategy to form quaternary stereogenic centers. While this transformation is dominated by the use of second- and third-row transition metals (e.g., Pd, Rh, and Ir), recent developments have revealed the potential of first-row transition metals, which provide not only a less expensive and potentially equally efficient alternative but also new mechanistic possibilities. This review summarizes examples for the assembly of quaternary stereocenters using prochiral allylic substrates and hard, achiral nucleophiles in the presence of copper complexes and highlights the complementary approaches with soft, prochiral nucleophiles catalyzed by chiral cobalt and nickel complexes.
Identifiants
pubmed: 33570909
doi: 10.1021/acs.chemrev.0c01115
pmc: PMC8846597
mid: NIHMS1746780
doi:
Substances chimiques
Allyl Compounds
0
Coordination Complexes
0
Ligands
0
Solvents
0
Transition Elements
0
Types de publication
Journal Article
Research Support, N.I.H., Extramural
Research Support, Non-U.S. Gov't
Review
Langues
eng
Sous-ensembles de citation
IM
Pagination
4084-4099Subventions
Organisme : NIGMS NIH HHS
ID : R01 GM080269
Pays : United States
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