Controlling the Reactivity of Copper(II) Acylperoxide Complexes.
Journal
Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543
Informations de publication
Date de publication:
21 Jun 2021
21 Jun 2021
Historique:
pubmed:
14
4
2021
medline:
14
7
2021
entrez:
13
4
2021
Statut:
ppublish
Résumé
The redox state of the metallomonooxygenases is finely tuned by imposing specific coordination environments on the metal center to reduce the activation energy for the generation of active-oxygen species and subsequent substrate oxygenation reactions. In this study, copper(II) complexes supported by a series of linear tetradentate ligands consisting of a rigid 6-, 7-, or 8-membered cyclic diamine with two pyridylmethyl (-CH
Identifiants
pubmed: 33848148
doi: 10.1021/acs.inorgchem.1c00475
doi:
Substances chimiques
Coordination Complexes
0
Ligands
0
Peroxides
0
Copper
789U1901C5
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM