Controlling the Reactivity of Copper(II) Acylperoxide Complexes.


Journal

Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543

Informations de publication

Date de publication:
21 Jun 2021
Historique:
pubmed: 14 4 2021
medline: 14 7 2021
entrez: 13 4 2021
Statut: ppublish

Résumé

The redox state of the metallomonooxygenases is finely tuned by imposing specific coordination environments on the metal center to reduce the activation energy for the generation of active-oxygen species and subsequent substrate oxygenation reactions. In this study, copper(II) complexes supported by a series of linear tetradentate ligands consisting of a rigid 6-, 7-, or 8-membered cyclic diamine with two pyridylmethyl (-CH

Identifiants

pubmed: 33848148
doi: 10.1021/acs.inorgchem.1c00475
doi:

Substances chimiques

Coordination Complexes 0
Ligands 0
Peroxides 0
Copper 789U1901C5

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

8554-8565

Auteurs

Yuma Morimoto (Y)

Department of Molecular Chemistry, Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.

Makito Kawai (M)

Department of Molecular Chemistry, Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.

Aya Nakanishi (A)

Department of Molecular Chemistry, Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.

Hideki Sugimoto (H)

Department of Molecular Chemistry, Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.

Shinobu Itoh (S)

Department of Molecular Chemistry, Division of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.

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Classifications MeSH