Preparation of a polymer-based weak cation exchanger for ion chromatography via atom transfer radical polymerization.

Acrylic acid Atom transfer radical polymerization Ion chromatography Maleic anhydride Weak cation exchanger

Journal

Journal of chromatography. A
ISSN: 1873-3778
Titre abrégé: J Chromatogr A
Pays: Netherlands
ID NLM: 9318488

Informations de publication

Date de publication:
05 Jul 2021
Historique:
received: 12 01 2021
revised: 12 04 2021
accepted: 18 04 2021
pubmed: 12 5 2021
medline: 8 6 2021
entrez: 11 5 2021
Statut: ppublish

Résumé

A novel polymer-based weak cation exchanger (WCX) for ion chromatography has been described. It was prepared by grafting tert-butyl acrylate and maleic anhydride onto the surface of poly(glycidyl methacrylate-divinylbenzene) microspheres via atom transfer radical polymerization, followed by hydrolytic treatment to produce acrylic and maleic acid groups. The obtained WCX showed better separation and higher selectivity for model cations relative to solely acrylic or maleic acid. Simultaneous separation of alkali and alkaline earth cations (including NH

Identifiants

pubmed: 33975083
pii: S0021-9673(21)00311-3
doi: 10.1016/j.chroma.2021.462187
pii:
doi:

Substances chimiques

Alkalies 0
Cation Exchange Resins 0
Polymers 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

462187

Informations de copyright

Copyright © 2021 Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Auteurs

Xuefang Liu (X)

Engineering Research Center of Pharmaceutical Process Chemistry, Ministry of Education, School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China.

Shuangshuang Pang (S)

Engineering Research Center of Pharmaceutical Process Chemistry, Ministry of Education, School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China.

Feifang Zhang (F)

Engineering Research Center of Pharmaceutical Process Chemistry, Ministry of Education, School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China. Electronic address: zhangff@ecust.edu.cn.

Zongying Li (Z)

Engineering Research Center of Pharmaceutical Process Chemistry, Ministry of Education, School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China.

Bingcheng Yang (B)

Engineering Research Center of Pharmaceutical Process Chemistry, Ministry of Education, School of Pharmacy, East China University of Science and Technology, Shanghai 200237, China. Electronic address: bcyang@ecust.edu.cn.

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Classifications MeSH