Daptomycin: A Novel Macrocyclic Antibiotic as a Chiral Selector in an Organic Polymer Monolithic Capillary for the Enantioselective Analysis of a Set of Pharmaceuticals.


Journal

Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009

Informations de publication

Date de publication:
09 Jun 2021
Historique:
received: 18 05 2021
revised: 01 06 2021
accepted: 04 06 2021
entrez: 2 7 2021
pubmed: 3 7 2021
medline: 30 7 2021
Statut: epublish

Résumé

Daptomycin, a macrocyclic antibiotic, is here used as a new chiral selector in preparation of chiral stationary phase (CSP) in a recently prepared polymer monolithic capillary. The latter is prepared using the copolymerization of the monomers glycidyl methacrylate (GMA) and ethylene glycol dimethacrylate (EGDMA) in the presence of daptomycin in water. Under reversed phase conditions (RP), the prepared capillaries were tested for the enantioselective nanoliquid chromatographic separation of fifty of the racemic drugs of different pharmacological groups, such as adrenergic blockers, H1-blockers, NSAIDs, antifungal drugs, and others. Baseline separation was attained for many drugs under RP-HPLC. Daptomycin expands the horizon of chiral selectors in HPLC.

Identifiants

pubmed: 34207780
pii: molecules26123527
doi: 10.3390/molecules26123527
pmc: PMC8227699
pii:
doi:

Substances chimiques

Anti-Bacterial Agents 0
Epoxy Compounds 0
Macrocyclic Compounds 0
Methacrylates 0
Polymers 0
ethylene dimethacrylate 7BK5G69305
Daptomycin NWQ5N31VKK
glycidyl methacrylate R8WN29J8VF

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

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Auteurs

Ali Fouad (A)

Chirality Program, Faculty of Science and Technology, University of Canberra, Bruce, Canberra 2601, Australia.
Pharmaceutical Chemistry Department, Faculty of Pharmacy, Al-Azhar University, Assiut 71524, Egypt.

Adel A Marzouk (AA)

Pharmaceutical Chemistry Department, Faculty of Pharmacy, Al-Azhar University, Assiut 71524, Egypt.

Montaser Sh A Shaykoon (MSA)

Pharmaceutical Chemistry Department, Faculty of Pharmacy, Al-Azhar University, Assiut 71524, Egypt.

Samy M Ibrahim (SM)

Pharmaceutical Chemistry Department, Faculty of Pharmacy, Zagazig University, Zagazig 44519, Egypt.

Sobhy M El-Adl (SM)

Pharmaceutical Chemistry Department, Faculty of Pharmacy, Zagazig University, Zagazig 44519, Egypt.

Ashraf Ghanem (A)

Chirality Program, Faculty of Science and Technology, University of Canberra, Bruce, Canberra 2601, Australia.

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Classifications MeSH