Modification of banana starch (Musa paradisiaca L.) with polyethylene terephthalate: Virgin and bottle waste.


Journal

Carbohydrate research
ISSN: 1873-426X
Titre abrégé: Carbohydr Res
Pays: Netherlands
ID NLM: 0043535

Informations de publication

Date de publication:
Oct 2021
Historique:
received: 17 02 2021
revised: 27 06 2021
accepted: 10 07 2021
pubmed: 20 7 2021
medline: 13 1 2022
entrez: 19 7 2021
Statut: ppublish

Résumé

Chemical modification of banana starch (Musa paradisiaca L.) with the degradation products of virgin and bottle waste of polyethylene terephthalate was carried out in situ. The modified starch was characterized by FTIR and NMR, which allowed proposing three chemical structures. SEM micrographs showed that the morphology of the modified starch granule is directly related with mass ratio of Starch/PET and type of PET used in the reaction. The crystallinity of the modified starch decreased up to 92.6% and 62.5% using bottle waste and virgin PET, respectively, according to XRD diffractograms. TGA analysis showed that the starch degradation temperature decreased by 12 °C. Modified starch films were elaborate and its electrical conductivity was found to be 2.9 times compared to that of native starch. The starch/PET film presented the highest value in the mechanical property of elongation at break compared to the starch-only film. The modified starch film was degraded above 80% by aqueous hydrolysis.

Identifiants

pubmed: 34280805
pii: S0008-6215(21)00170-1
doi: 10.1016/j.carres.2021.108401
pii:
doi:

Substances chimiques

Polyethylene Terephthalates 0
Starch 9005-25-8

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

108401

Informations de copyright

Copyright © 2021. Published by Elsevier Ltd.

Auteurs

Ramírez-Centeno Silvia (RC)

Universidad Del Papaloapan, Departamento de Química, Circuito Central 200, C.P. 68301, Tuxtepec, Oaxaca, Mexico. Electronic address: chivis_tkmas@hotmail.com.

Marcos-Fernández Angel (MF)

Instituto de Ciencia y Tecnología de Polímeros (ICTP), C/ Juan de La Cierva 3, 28006, Madrid, Spain. Electronic address: amarcos@ictp.csic.es.

Aparicio-Saguilán Alejandro (AS)

Universidad Del Papaloapan, Departamento de Química, Circuito Central 200, C.P. 68301, Tuxtepec, Oaxaca, Mexico. Electronic address: alejandrosag@hotmail.com.

Navarro-Crespo Rodrigo (NC)

Instituto de Ciencia y Tecnología de Polímeros (ICTP), C/ Juan de La Cierva 3, 28006, Madrid, Spain. Electronic address: rnavarro@ictp.csic.es.

Ramírez-Hernández Aurelio (RH)

Universidad Del Papaloapan, Departamento de Química, Circuito Central 200, C.P. 68301, Tuxtepec, Oaxaca, Mexico. Electronic address: chino_raha@hotmail.com.

Báez-García José Eduardo (BG)

Universidad de Guanajuato, División de Ciencias Exactas Departamento de Química, Noria Alta S/N; C.P. 36050. Guanajuato, Guanajuato, Mexico. Electronic address: jebaez14@yahoo.com.mx.

Delia Esther Páramo Calderón (DE)

Universidad Del Papaloapan, Departamento de Química, Circuito Central 200, C.P. 68301, Tuxtepec, Oaxaca, Mexico. Electronic address: de_paramo@yahoo.com.mx.

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Classifications MeSH