Hyperbranched anion exchangers prepared from polyethylene polyamine modified polymeric substrates for ion chromatography.
Anion exchanger
Exhaled breath condensate
Hyperbranched condensation polymer
Ion chromatography
Polyethylene polyamine
Journal
Journal of chromatography. A
ISSN: 1873-3778
Titre abrégé: J Chromatogr A
Pays: Netherlands
ID NLM: 9318488
Informations de publication
Date de publication:
11 Oct 2021
11 Oct 2021
Historique:
received:
22
06
2021
revised:
25
08
2021
accepted:
26
08
2021
pubmed:
8
9
2021
medline:
25
11
2021
entrez:
7
9
2021
Statut:
ppublish
Résumé
High hydrophilic anion stationary phases play a crucial role in the separation behavior of ion chromatography. Herein, we report novel polymeric anion exchangers grafted with polyethylene polyamines, including ethylenediamine, diethylenetriamine, triethylenetetramine and tetraethylene pentaamine, via a facile epoxy-amine polymerization method. The anion exchangers were characterized by scanning electron microscopy, thermogravimetry, Fourier transform infrared spectrometry and elemental analysis. The chromatographic performance of the stationary phases was evaluated with the separation of common inorganic anions, organic weak acids and highly polarizable anions. Seven common anions (F
Identifiants
pubmed: 34492579
pii: S0021-9673(21)00632-4
doi: 10.1016/j.chroma.2021.462508
pii:
doi:
Substances chimiques
Anions
0
Polyamines
0
Polyethylenes
0
polyethylene polyamine
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
462508Informations de copyright
Copyright © 2021. Published by Elsevier B.V.
Déclaration de conflit d'intérêts
Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.