Degradation of oxytetracycline in aqueous solution by heat-activated peroxydisulfate and peroxymonosulfate oxidation.
Antibiotic
Hydroxyl radicals
Peroxymonosulfate activation
Persulfate activation
Sulfate radicals
Journal
Environmental science and pollution research international
ISSN: 1614-7499
Titre abrégé: Environ Sci Pollut Res Int
Pays: Germany
ID NLM: 9441769
Informations de publication
Date de publication:
Feb 2022
Feb 2022
Historique:
received:
18
01
2021
accepted:
20
08
2021
pubmed:
9
9
2021
medline:
27
1
2022
entrez:
8
9
2021
Statut:
ppublish
Résumé
Oxytetracycline (OTC) is a broad-spectrum antibiotic that resists biodegradation and poses a risk to the ecosystem. This study investigated the degradation of OTC by heat-activated peroxydisulfate (PDS) and peroxymonosulfate (PMS) processes. Response surface methodology (RSM) was used to evaluate the effect of process parameters, namely initial pH, oxidant concentration, temperature, and reaction time on the OTC removal efficiency. According to the results of the RSM models, all four independent variables were significant for both PDS and PMS processes. The optimum process parameters for the heat-activated PDS process were pH 8.9, PDS concentration 3.9 mM, temperature 72.9°C, and reaction time 26.5 min. For the heat-activated PMS process, optimum conditions were pH 9.0, PMS concentration 4.0 mM, temperature 75.0°C, and reaction time 20.0 min. The predicted OTC removal efficiencies for the PDS and PMS processes were 89.7% and 84.0%, respectively. As a result of the validation experiments conducted at optimum conditions, the obtained OTC removal efficiencies for the PDS and PMS processes were 87.6 ± 4.2 and 80.2± 4.6, respectively. PDS process has higher kinetic constants at all pH values than the PMS process. Both processes were effective in OTC removal from aqueous solution and RSM was efficient in process optimization.
Identifiants
pubmed: 34495474
doi: 10.1007/s11356-021-16157-7
pii: 10.1007/s11356-021-16157-7
doi:
Substances chimiques
Peroxides
0
Sulfates
0
Water Pollutants, Chemical
0
peroxymonosulfate
22047-43-4
Oxytetracycline
X20I9EN955
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
9110-9123Subventions
Organisme : h2020 marie skłodowska-curie actions
ID : 898422
Informations de copyright
© 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
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