Permanganate oxidation of polycyclic aromatic compounds (PAHs and polar PACs): column experiments with DNAPL at residual saturation.
Column flow-through experiments
Dense nonaqueous phase liquid
O-PAC ketones
Potassium permanganate
Soil and groundwater remediation
Journal
Environmental science and pollution research international
ISSN: 1614-7499
Titre abrégé: Environ Sci Pollut Res Int
Pays: Germany
ID NLM: 9441769
Informations de publication
Date de publication:
Mar 2022
Mar 2022
Historique:
received:
15
03
2021
accepted:
21
09
2021
pubmed:
14
10
2021
medline:
12
2
2022
entrez:
13
10
2021
Statut:
ppublish
Résumé
Permanganate is an oxidant usually applied for in situ soil remediation due to its persistence underground. It has already shown great efficiency for dense nonaqueous phase liquid (DNAPL) degradation under batch experiment conditions. In the present study, experimental permanganate oxidation of a DNAPL - coal tar - sampled in the groundwater of a former coking plant was carried out in a glass bead column. Several glass bead columns were spiked with coal tar using the drainage-imbibition method to mimic on-site pollution spread at residual saturation as best as possible. The leaching of organic pollutants was monitored as the columns were flushed by successive sequences: successive injections of hot water, permanganate solution for oxidation, and ambient temperature water, completed by two injections of a tracer before and after oxidation. Sixteen conventional US-EPA PAHs and selected polar PACs were analyzed in the DNAPL remaining in the columns at the end of the experiment and in the particles collected at several steps of the flushing sequences. Permanganate oxidation of the pollutants was rapidly limited by interfacial aging of the DNAPL drops. Moreover, at the applied flow rate chosen to be representative of in situ injections and groundwater velocities, the reaction time was not sufficient to reach high degradation yields but induced the formation and the leaching of oxygenated PACs.
Identifiants
pubmed: 34642882
doi: 10.1007/s11356-021-16717-x
pii: 10.1007/s11356-021-16717-x
doi:
Substances chimiques
Manganese Compounds
0
Oxides
0
Polycyclic Aromatic Hydrocarbons
0
Polycyclic Compounds
0
Water Pollutants, Chemical
0
permanganic acid
14333-13-2
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
15966-15982Informations de copyright
© 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
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