Apple juice and red wine induced mirror-image circular dichroism in quantum dots.
apple juice
chiral nanoparticles
chiral semiconductors
circular dichroism
malic acid
quantum dots
tartaric acid
wine
Journal
Chirality
ISSN: 1520-636X
Titre abrégé: Chirality
Pays: United States
ID NLM: 8914261
Informations de publication
Date de publication:
01 2022
01 2022
Historique:
revised:
05
10
2021
received:
26
08
2021
accepted:
09
10
2021
pubmed:
29
10
2021
medline:
22
1
2022
entrez:
28
10
2021
Statut:
ppublish
Résumé
Juices, wines, and extracts from plants contain high concentrations of various chiral compounds such as carboxylic acids or sugars. Several prior studies reported the synthesis of metallic and semiconducting nanoparticles relying on components of complex biological solutions. Herein, we present preparation of chiral CdS and CdSe quantum dots (QDs) using apple juice and red wine via phase transfer ligand exchange. Although both apple juice and red wine contain a complex mixture of chiral and achiral compounds, we have successfully used them for selective induction of predicted chiroptical properties and confirmed L-malic acid from the apple juice and L-tartaric acid from the red wine as the chiral inducers. This work illustrates the capability of using complex mixtures to construct chiral QDs with desired chiroptical properties as well as potential of QDs to selectively report a chiral molecule in a complex chiral mixture without the need for elaborate chiral recognition system.
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
70-76Subventions
Organisme : CBET
ID : 1403947
Informations de copyright
© 2021 Wiley Periodicals LLC.
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