Block-Copolymers Enable Direct Reduction and Structuration of Noble Metal-Based Films.
block-copolymers
mesoporous films
metals
patterning
reduction
small-angle X-ray scattering
Journal
Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338
Informations de publication
Date de publication:
02 2022
02 2022
Historique:
revised:
08
10
2021
received:
18
07
2021
pubmed:
26
11
2021
medline:
19
3
2022
entrez:
25
11
2021
Statut:
ppublish
Résumé
Noble metal nanostructured films are of great interest for various applications including electronics, photonics, catalysis, and photocatalysis. Yet, structuring and patterning noble metals, especially those of the platinum group, is challenging by conventional nanofabrication. Herein, an approach based on solution processing to obtain metal-based films (rhodium, ruthenium (Ru) or iridium in the presence of residual organic species) with nanostructuration at the 20 nm-scale is introduced. Compared to existing approaches, the dual functionality of block-copolymers acting both as structuring and as reducing agent under inert atmosphere is exploited. A set of in situ techniques has allowed for the capturing of the carbothermal reduction mechanism occurring at the hybrid organic/inorganic interface. Differently from previous literature, a two-step reduction mechanism is unveiled with the formation of a carbonyl intermediate. From a technological point of view, the materials can be solution-processed on a large scale by dip-coating as polymers and simultaneously structured and reduced into metals without requiring expensive equipment or treatments in reducing atmosphere. Importantly, the metal-based films can be patterned directly by block-copolymer lithography or by soft-nanoimprint lithography on various substrates. As proof-of-concept of application, the authors demonstrate that nanostructured Ru films can be used as efficient catalysts for H
Identifiants
pubmed: 34821023
doi: 10.1002/smll.202104204
doi:
Substances chimiques
Metals
0
Polymers
0
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2104204Informations de copyright
© 2021 Wiley-VCH GmbH.
Références
R. J. Seymour, J. O'Farrelly, in Kirk-Othmer Encyclopedia of Chemical Technology, 2012, p. 1, https://onlinelibrary.wiley.com/action/showCitFormats?doi=10.1002%2F0471238961.1612012019052513.a01.pub3.
M. Odziomek, M. Bahri, C. Boissière, C. Sanchez, B. Lassalle-Kaiser, A. Zitolo, O. Ersen, S. Nowak, C. Tard, M. Giraud, M. Faustini, J. Peron, Mater. Horiz. 2020, 7, 541.
P. B. Kettler, Org. Process Res. Dev. 2003, 7, 342.
T. Reier, M. Oezaslan, P. Strasser, ACS Catal. 2012, 2, 1765.
a) M. Ming, Y. Zhang, C. He, L. Zhao, S. Niu, G. Fan, J.-S. Hu, Small 2019, 15, 1903057;
b) H. Wang, H. D. Abruña, ACS Catal. 2019, 9, 5057.
H.-I. Ryoo, J. S. Lee, C. B. Park, D.-P. Kim, Lab Chip 2011, 11, 378.
K. C. Basavaraju, S. Sharma, R. A. Maurya, D. P. Kim, Angew. Chem. 2013, 125, 6867.
A. M. Watson, X. Zhang, R. Alcaraz de la Osa, J. M. Sanz, F. González, F. Moreno, G. Finkelstein, J. Liu, H. O. Everitt, Nano Lett. 2015, 15, 1095.
a) L. G. Wen, C. Adelmann, O. V. Pedreira, S. Dutta, M. Popovici, B. Briggs, N. Heylen, K. Vanstreels, C. J. Wilson, S. Van Elshocht, in 2016 IEEE Int. Interconnect Technology Conf./Advanced Metallization Conf. (IITC/AMC), IEEE, Piscataway, NJ 2016;
b) T. N. Arunagiri, Y. Zhang, O. Chyan, M. El-Bouanani, M. J. Kim, K. H. Chen, C. T. Wu, L. C. Chen, Appl. Phys. Lett. 2005, 86, 083104.
A. C. Probst, T. Döhring, M. Stollenwerk, M. Wen, L. Proserpio, in Int. Conf. on Space Optics-ICSO 2016, SPIE, Bellingham, WA 2017.
A. Mallavarapu, P. Ajay, C. Barrera, S. V. Sreenivasan, ACS Appl. Mater. Interfaces 2021, 13, 1169.
a) R. Glass, M. Möller, J. P. Spatz, Nanotechnology 2003, 14, 1153;
b) J. Chai, F. Huo, Z. Zheng, L. R. Giam, W. Shim, C. A. Mirkin, Proc. Natl. Acad. Sci. USA 2010, 107, 20202;
c) L. Huang, P.-C. Chen, M. Liu, X. Fu, P. Gordiichuk, Y. Yu, C. Wolverton, Y. Kang, C. A. Mirkin, Proc. Natl. Acad. Sci. USA 2018, 115, 3764;
d) L. Huang, H. Lin, C. Y. Zheng, E. J. Kluender, R. Golnabi, B. Shen, C. A. Mirkin, J. Am. Chem. Soc. 2020, 142, 4570;
e) L. Chen, X. Wei, X. Zhou, Z. Xie, K. Li, Q. Ruan, C. Chen, J. Wang, C. A. Mirkin, Z. Zheng, Small 2017, 13, 1702003;
f) R. Guo, Y. Yu, Z. Xie, X. Liu, X. Zhou, Y. Gao, Z. Liu, F. Zhou, Y. Yang, Z. Zheng, Adv. Mater. 2013, 25, 3343;
g) Y. Yu, X. Xiao, Y. Zhang, K. Li, C. Yan, X. Wei, L. Chen, H. Zhen, H. Zhou, S. Zhang, Adv. Mater. 2016, 28, 4926;
h) Y. Yu, C. Yan, Z. Zheng, Adv. Mater. 2014, 26, 5508.
a) B. Jiang, C. Li, M. Imura, J. Tang, Y. Yamauchi, Adv. Sci. 2015, 2, 1500112;
b) C. Li, Ö. Dag, T. D. Dao, T. Nagao, Y. Sakamoto, T. Kimura, O. Terasaki, Y. Yamauchi, Nat. Commun. 2015, 6, 1;
c) G. S. Attard, P. N. Bartlett, N. R. B. Coleman, J. M. Elliott, J. R. Owen, J. H. Wang, Science 1997, 278, 838.
a) L. Longenberger, G. Mills, J. Phys. Chem. 1995, 99, 475;
b) T. Sakai, P. Alexandridis, J. Phys. Chem. B 2005, 109, 7766;
c) T. Sakai, Y. Horiuchi, P. Alexandridis, T. Okada, S. Mishima, J. Colloid Interface Sci. 2013, 394, 124;
d) P. Alexandridis, Chem. Eng. Technol. 2011, 34, 15;
e) M. Faustini, L. Nicole, E. Ruiz-Hitzky, C. Sanchez, Adv. Funct. Mater. 2018, 28, 1704158.
T. Sakai, P. Alexandridis, Langmuir 2004, 20, 8426.
M. Grobis, C. Schulze, M. Faustini, D. Grosso, O. Hellwig, D. Makarov, M. Albrecht, Appl. Phys. Lett. 2011, 98, 192504-1.
V. Neu, C. Schulze, M. Faustini, J. Lee, D. Makarov, D. Suess, S. K. Kim, D. Grosso, L. Schultz, M. Albrecht, Nanotechnology 2013, 24, 145702-1.
M. Gayrard, J. Voronkoff, C. Boissière, D. Montero, L. Rozes, A. Cattoni, J. Peron, M. Faustini, Nano Lett. 2021, 21, 2310.
M. Faustini, B. Marmiroli, L. Malfatti, B. Louis, N. Krins, P. Falcaro, G. Grenci, C. Laberty-Robert, H. Amenitsch, P. Innocenzi, D. Grosso, J. Mater. Chem. 2011, 21, 3597.
M. Faustini, D. Grosso, C. R. Chim. 2016, 19, 248.
a) M. Kuemmel, J. Allouche, L. Nicole, C. Boissière, C. Laberty, H. Amenitsch, C. Sanchez, D. Grosso, Chem. Mater. 2007, 19, 3717;
b) M. Kuemmel, J.-H. Smått, C. Boissière, L. Nicole, C. Sanchez, M. Lindén, D. Grosso, J. Mater. Chem. 2009, 19, 3638.
M. Faustini, G. L. Drisko, A. A. Letailleur, R. S. Montiel, C. Boissiere, A. Cattoni, A. M. Haghiri-Gosnet, G. Lerondel, D. Grosso, Nanoscale 2013, 5, 984.
E. Bindini, G. Naudin, M. Faustini, D. Grosso, C. Boissière, J. Phys. Chem. C 2017, 121, 14572.
F. T. L. Muniz, M. A. R. Miranda, C. Morilla dos Santos, J. M. Sasaki, Acta Crystallogr., Sect. A: Found. Adv. 2016, 72, 385.
R. M. Silverstein, G. C. Bassler, J. Chem. Educ. 1962, 39, 546.
K. Pielichowski, K. Flejtuch, J. Anal. Appl. Pyrolysis 2005, 73, 131.
a) X.-M. Li, H.-L. Liu, X. Liu, N. Fang, X.-H. Wang, J.-H. Wu, Sci. Rep. 2015, 5, 1;
b) B. Jiang, C. Li, Ö. Dag, H. Abe, T. Takei, T. Imai, M. S. A. Hossain, M. T. Islam, K. Wood, J. Henzie, Nat. Commun. 2017, 8, 1.
E. Cariati, C. Dragonetti, D. Roberto, R. Ugo, E. Lucenti, Inorg. Chim. Acta 2003, 349, 189.
R. Psaro, D. Roberto, R. Ugo, C. Dossi, A. Fusi, J. Mol. Catal. 1992, 74, 391.
a) C. P. Booker, J. T. Keiser, J. Phys. Chem. 1989, 93, 1532;
b) M. I. Zaki, B. Tesche, L. Kraus, H. Knözinger, Surf. Interface Anal. 1988, 12, 239.
a) J. T. Yates Jr., K. Kolasinski, J. Chem. Phys. 1983, 79, 1026;
b) D. I. Kondarides, Z. Zhang, X. E. Verykios, J. Catal. 1998, 176, 536.
M. Faustini, A. Grenier, G. Naudin, R. Li, D. Grosso, Nanoscale 2015, 7, 19419.
R. Li, M. Boudot, C. Boissière, D. Grosso, M. Faustini, ACS Appl. Mater. Interfaces 2017, 9, 14093.
A. Guiet, T. Reier, N. Heidary, D. Felkel, B. Johnson, U. Vainio, H. Schlaad, Y. Aksu, M. Driess, P. Strasser, Chem. Mater. 2013, 25, 4645.
C. Luo, X. Ni, L. Liu, S. i. M. Nomura, Y. Chen, Biotechnol. Bioeng. 2010, 105, 854.
H.-L. Chen, A. Cattoni, R. De Lépinau, A. W. Walker, O. Höhn, D. Lackner, G. Siefer, M. Faustini, N. Vandamme, J. Goffard, Nat. Energy 2019, 4, 761.
a) A. Cattoni, P. Ghenuche, A.-M. Haghiri-Gosnet, D. Decanini, J. Chen, J.-L. Pelouard, S. p. Collin, Nano Lett. 2011, 11, 3557;
b) T. Bottein, O. Dalstein, M. Putero, A. Cattoni, M. Faustini, M. Abbarchi, D. Grosso, Nanoscale 2018, 10, 1420.
O. Dalstein, D. R. Ceratti, C. Boissière, D. Grosso, A. Cattoni, M. Faustini, Adv. Funct. Mater. 2016, 26, 81.
H. N. Abdelhamid, Int. J. Hydrogen Energy 2020, 46, 726.
Y. Shang, R. Chen, Energy Fuels 2006, 20, 2149.
D.-H. Ko, W. Ren, J.-O. Kim, J. Wang, H. Wang, S. Sharma, M. Faustini, D.-P. Kim, ACS Nano 2016, 10, 1156.
M. Faustini, J. Kim, G.-Y. Jeong, J. Y. Kim, H. R. Moon, W.-S. Ahn, D.-P. Kim, J. Am. Chem. Soc. 2013, 135, 14619.
M. Faustini, A. Cattoni, J. Peron, C. Boissière, P. Ebrard, A. Malchère, P. Steyer, D. Grosso, ACS Nano 2018, 12, 3243.
H. Amenitsch, M. Rappolt, M. Kriechbaum, H. Mio, P. Laggner, S. Bernstorff, J. Synchrotron Radiat. 1998, 5, 506.
M. Burian, C. Meisenbichler, D. Naumenko, H. Amenitsch, arXiv:2007.02022 2020.