The impact of individual human cytochrome P450 enzymes on oxidative metabolism of anticancer drug lenvatinib.


Journal

Biomedicine & pharmacotherapy = Biomedecine & pharmacotherapie
ISSN: 1950-6007
Titre abrégé: Biomed Pharmacother
Pays: France
ID NLM: 8213295

Informations de publication

Date de publication:
Jan 2022
Historique:
received: 03 09 2021
revised: 20 10 2021
accepted: 02 11 2021
pubmed: 1 12 2021
medline: 15 3 2022
entrez: 30 11 2021
Statut: ppublish

Résumé

Lenvatinib, a small molecule tyrosine kinase inhibitor (TKI), exhibits good inhibitory effect in several types of carcinomas. Specifically, it is the most effective TKI used for treatment of thyroid cancer. To extend pharmacokinetics data on this anticancer agent, we aimed to identify the metabolites of lenvatinib formed during in vitro incubation of lenvatinib with human hepatic microsomes or recombinant cytochromes P450 (CYPs) by using high performance liquid chromatography and mass spectrometry. The role of CYPs in the oxidation of lenvatinib was initially investigated in hepatic microsomes using specific CYP inhibitors. CYP-catalytic activities in each microsomal sample were correlated with the amounts of lenvatinib metabolites formed by these samples. Further, human recombinant CYPs were employed in the metabolic studies. Based on our data, lenvatinib is metabolized to O-desmethyl lenvatinib, N-descyclopropyl lenvatinib and lenvatinib N-oxide. In the presence of cytochrome b

Identifiants

pubmed: 34847475
pii: S0753-3322(21)01177-X
doi: 10.1016/j.biopha.2021.112391
pii:
doi:

Substances chimiques

Antineoplastic Agents 0
Cytochrome P-450 Enzyme Inhibitors 0
Phenylurea Compounds 0
Protein Kinase Inhibitors 0
Quinolines 0
Cytochrome P-450 Enzyme System 9035-51-2
lenvatinib EE083865G2

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

112391

Informations de copyright

Copyright © 2021 The Authors. Published by Elsevier Masson SAS.. All rights reserved.

Auteurs

Katarína Vavrová (K)

Department of Biochemistry, Faculty of Science, Charles University, Albertov 6, 128 00 Prague 2, Czech Republic.

Radek Indra (R)

Department of Biochemistry, Faculty of Science, Charles University, Albertov 6, 128 00 Prague 2, Czech Republic. Electronic address: radek.indra@natur.cuni.cz.

Petr Pompach (P)

Department of Biochemistry, Faculty of Science, Charles University, Albertov 6, 128 00 Prague 2, Czech Republic.

Zbyněk Heger (Z)

Department of Chemistry and Biochemistry, Mendel University in Brno, Zemedelska 1, 613 00 Brno, Czech Republic; Central European Institute of Technology, Brno University of Technology, Purkynova 656/123, 612 00 Brno, Czech Republic.

Petr Hodek (P)

Department of Biochemistry, Faculty of Science, Charles University, Albertov 6, 128 00 Prague 2, Czech Republic.

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Classifications MeSH