Investigation of different alcoholic modifiers for the separation and determination of two isomers of dinitrotoluene (2,4 and 2,6) by ion mobility spectrometry.
Journal
Rapid communications in mass spectrometry : RCM
ISSN: 1097-0231
Titre abrégé: Rapid Commun Mass Spectrom
Pays: England
ID NLM: 8802365
Informations de publication
Date de publication:
30 May 2022
30 May 2022
Historique:
revised:
04
12
2021
received:
05
09
2021
accepted:
31
01
2022
pubmed:
19
2
2022
medline:
22
4
2022
entrez:
18
2
2022
Statut:
ppublish
Résumé
Some alcoholic modifier gases were applied to separate isomer peaks in ion mobility spectrometry (IMS). Different mechanisms have been investigated on the separation, such as collision cross-section and analyte-modifier cluster formation. In this regard, some parameters that affected the cluster formation, such as dipole moment, electron affinity, the position of functional groups, and the modifier structure, were evaluated. On the other hand, some effective experimental parameters, including cell temperature and the flow rates of the drift and modifier gases, were also optimized. The combination of dispersive liquid-liquid microextraction with thin-film evaporation (DLLME-TFE) was used as a sample preparation method for the extraction of 2,4-dinitrotoluene (2,4-DNT) and 2,6-dinitrotoluene (2,6-DNT) isomers (as the target analytes). Isobutanol was selected as the alcoholic modifier to separate the ion molecular peaks of these isomers. The limit of detection and the limit of quantification obtained were 15 and 50 μg L
Substances chimiques
Dinitrobenzenes
0
Gases
0
Waste Water
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e9274Subventions
Organisme : Isfahan University of Technology
Organisme : the Research Council
Informations de copyright
© 2022 John Wiley & Sons Ltd.
Références
Puton J, Namieśnik J. Ion mobility spectrometry: Current status and application for chemical warfare agents detection. Trends Anal Chem. 2016;85:10-20. doi:10.1016/j.trac.2016.06.002
Mu Y, Schulz BL, Ferro V. Applications of ion mobility-mass spectrometry in carbohydrate chemistry and glycobiology. Molecules. 2018;23(10):2557. doi:10.3390/molecules23102557
Jafari MT, Saraji M, Sherafatmand H. Design for gas chromatography-corona discharge-ion mobility spectrometry. Anal Chem. 2012;84(22):10077-10084. doi:10.1021/ac3025398
Armenta S, Alcala M, Blanco M. A review of recent, unconventional applications of ion mobility spectrometry (IMS). Anal Chim Acta. 2011;703(2):114-123. doi:10.1016/j.aca.2011.07.021
Waraksa E, Perycz U, Namieśnik J, et al. Dopants and gas modifiers in ion mobility spectrometry. Trends Anal Chem. 2016;82:237-249. doi:10.1016/j.trac.2016.06.009
Dodds JN, May JC, McLean JA. Correlating resolving power, resolution, and collision cross section: Unifying cross-platform assessment of separation efficiency in ion mobility spectrometry. Anal Chem. 2017;89(22):12176-12184. doi:10.1021/acs.analchem.7b02827
Fernández-Maestre R, Meza-Morelos D, Hill HH. Mobilities of amino acid adducts with modifiers in the buffer gas of an ion mobility spectrometer depended on modifier size and modifier-amino acid interaction energy. Int J Mass Spectrom. 2015;380:21-25. doi:10.1016/j.ijms.2015.03.003
Fernández-Maestre R, Meza-Morelos D, Wu C. Mobility shifts when buffer gas temperature increases in ion mobility spectrometry are affected by intramolecular bonds. Int J Mass Spectrom. 2016;407:113-117. doi:10.1016/j.ijms.2016.06.012
Jafari MT, Riahi F. Feasibility of corona discharge ion mobility spectrometry for direct analysis of samples extracted by dispersive liquid-liquid microextraction. J Chromatogr A. 2014;1343:63-68. doi:10.1016/j.chroma.2014.03.069
Dwivedi P, Wu C, Matz LM, Clowers BH, Siems WF, Hill HH. Gas-phase chiral separations by ion mobility spectrometry. Anal Chem. 2006;78(24):8200-8206. doi:10.1021/ac0608772
Shvartsburg AA, Creese AJ, Smith RD, Cooper HJ. Separation of peptide isomers with variant modified sites by high-resolution differential ion mobility spectrometry. Anal Chem. 2010;82(19):8327-8334. doi:10.1021/ac101878a
Fernández-Maestre R, Wu C, Hill HHJ. Buffer gas modifiers effect resolution in ion mobility spectrometry through selective ion-molecule clustering reactions. Rapid Commun Mass Spectrom. 2012;26(19):2211-2223. doi:10.1002/rcm.6335
Lalli PM, Corilo YE, Fasciotti M, et al. Baseline resolution of isomers by traveling wave ion mobility mass spectrometry: Investigating the effects of polarizable drift gases and ionic charge distribution. J Mass Spectrom. 2013;48(9):989-997. doi:10.1002/jms.3245
Wei MS, Kemperman RHJ, Yost RA. Effects of solvent vapor modifiers for the separation of opioid isomers in micromachined FAIMS-MS. J Am Soc Mass Spectrom. 2019;30(5):731-742. doi:10.1007/s13361-019-02175-w
Rezayat MR, Jafari MT, Rahmanian F. Thin film nanofibers containing ZnTiO3 nanoparticles for rapid evaporation of extraction solvent: Application to the preconcentration of chlorpyrifos prior to its quantification by ion mobility spectrometry. Microchim Acta. 2019;186(1):35. doi:10.1007/s00604-018-3167-x
Lendenmann U, Spain JC, Smets BF. Simultaneous biodegradation of 2,4-dinitrotoluene and 2,6-dinitrotoluene in an aerobic fluidized-bed biofilm reactor. Environ Sci Technol. 1998;32(1):82-87. doi:10.1021/es970281j
Crestoni ME, Chiavarino B, Steinmetz V, Fornarini S. Communication: Vibrational study of a benzyl carbanion: Deprotonated 2,4-dinitrotoluene. J Chem Phys. 2012;137(18):181101. doi:10.1063/1.4767393
Jafari MT, Rezayat MR, Mossaddegh M. Design and construction of an injection port for coupling stir-bar sorptive extraction with ion mobility spectrometry. Talanta. 2018;178:369-376. doi:10.1016/j.talanta.2017.09.061
Rezayat MR, Jafari MT. Organic solvent supported silica aerogel thin film microextraction: An efficient sample preparation method for ion mobility spectrometry. Microchem J. 2020;159:105551. doi:10.1016/j.microc.2020.105551
Hariri M, Ghani K, Damiri S. Purification of 2,4,6-trinitrotoluene by digestion with sodium sulfite and determination of its impurities by gas chromatography-electron capture detector (GC-ECD). J Iran Chem Soc. 2019;16(11):2401-2408. doi:10.1007/s13738-019-01709-z
Jafari MT. Improved design for high resolution electrospray ionization ion mobility spectrometry. Talanta. 2009;77(5):1632-1639. doi:10.1016/j.talanta.2008.09.059
Frisch MJ, Trucks GW, Schlegel HB, et al. Gaussian 09; 2009. http://www.gaussian.com/
Rienstra-Kiracofe JC, Tschumper GS, Schaefer HF, Nandi S, Ellison GB. Atomic and molecular electron affinities: Photoelectron experiments and theoretical computations. Chem Rev. 2002;102(1):231-282. doi:10.1021/cr990044u
Chen PC, Lo W, Hu KH. Ab initio studies of the molecular structures of dinitrotoluenes. J Mol Struct (THEOCHEM). 1997;389(1-2):91-96.
Berton P, Regmi BP, Spivak DA, Warner IM. Ionic liquid-based dispersive microextraction of nitrotoluenes in water samples. Microchim Acta. 2014;181(11-12):1191-1198. doi:10.1007/s00604-014-1261-2