Comparison of pyrazines formation in methionine/glucose and corresponding Amadori rearrangement product model.
2,3-Diethylpyrazine (PubChem CID27458)
2,3-Dimethylpyrazine (PubChem CID22201)
2,5-Dimethylpyrazine (PubChem CID31252)
2,6-Dimethylpyrazine (PubChem CID7938)
2-Ethyl-3,5-dimethylpyrazine (PubChem CID26334)
2-Ethyl-5-methylpyrazine (PubChem CID25915)
Acetylpyrazine (PubChem CID30914)
Amadori rearrangement product
Ethylpyrazine (PubChem CID26331)
Methional
Methional (PubChem CID18635)
Methionine
Methylpyrazine (PubChem CID7976)
Pyrazine (PubChem CID9261)
Pyrazines
Trimethylpyrazine (PubChem CID26808)
Vinylpyrazine (PubChem CID77840)
d-Glucose (PubChem CID5793)
dl-methionine (PubChem CID876)
α-Dicarbonyl compounds
Journal
Food chemistry
ISSN: 1873-7072
Titre abrégé: Food Chem
Pays: England
ID NLM: 7702639
Informations de publication
Date de publication:
15 Jul 2022
15 Jul 2022
Historique:
received:
18
10
2021
revised:
14
02
2022
accepted:
15
02
2022
pubmed:
5
3
2022
medline:
1
4
2022
entrez:
4
3
2022
Statut:
ppublish
Résumé
The generation of pyrazines in a binary methionine/glucose (Met/Glc) mixture and corresponding methionine/glucose-derived Amadori rearrangement product (MG-ARP) was studied. Quantitative analyses of pyrazines and methional revealed that MG-ARP generated more methional compared to Met/Glc, whereas lower content and fewer species of pyrazines were observed in the MG-ARP model. Comparing the availability of α-dicarbonyl compounds generated from the Met/Glc model, methylglyoxal (MGO) was a considerably effective α-dicarbonyl compound for the formation of pyrazines during MG-ARP degradation, but glyoxal (GO) produced from MG-ARP did not effectively participate in the corresponding formation of pyrazines due to the asynchrony on the formation of GO and recovered Met. Diacetyl (DA) content was not high enough to form corresponding pyrazines in the MG-ARP model. The insufficient interaction of precursors and rapid drops in pH limited the formation of pyrazines during MG-ARP degradation. Increasing reaction temperature could reduce the negative inhibitory effect by promoting the content of precursors.
Identifiants
pubmed: 35245757
pii: S0308-8146(22)00462-9
doi: 10.1016/j.foodchem.2022.132500
pii:
doi:
Substances chimiques
Pyrazines
0
Glyoxal
50NP6JJ975
Methionine
AE28F7PNPL
Glucose
IY9XDZ35W2
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
132500Informations de copyright
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