Selective carbon-phosphorus bond cleavage: expanding the toolbox for accessing bulky divalent lanthanoid sandwich complexes.

Carbon / chemistry Europium Lanthanoid Series Elements / chemistry Phosphorus Samarium

Journal

Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838

Informations de publication

Date de publication:
31 Mar 2022
Historique:
pubmed: 17 3 2022
medline: 5 4 2022
entrez: 16 3 2022
Statut: epublish

Résumé

The synthesis of two new tetra- and penta-phenycyclopentadienyldiphenylphosphine pro-ligands which readily undergo selective C-P bond cleavage has allowed for the facile synthesis of bulky divalent octa- and deca-phenylmetallocenes of europium, ytterbium and samarium.

Identifiants

DOI: 10.1039/d2cc00698g PMID: 35293913
pubmed: 35293913
doi: 10.1039/d2cc00698g
doi:

Substances chimiques

Lanthanoid Series Elements 0
Phosphorus 27YLU75U4W
Samarium 42OD65L39F
Europium 444W947O8O
Carbon 7440-44-0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

4344-4347

Auteurs

Angus C G Shephard (ACG)

College of Science & Engineering, James Cook University, Townsville, QLD, 4811, Australia. peter.junk@jcu.edu.au.

Daisy P Daniels (DP)

School of Chemistry, Monash University, Clayton, VIC, 3800, Australia.

Glen B Deacon (GB)

School of Chemistry, Monash University, Clayton, VIC, 3800, Australia.
ORCID: 0000-0002-6966-6121

Zhifang Guo (Z)

College of Science & Engineering, James Cook University, Townsville, QLD, 4811, Australia. peter.junk@jcu.edu.au.

Florian Jaroschik (F)

ICGM, Univ Montpellier, CNRS, ENSCM, Montpellier, France.

Peter C Junk (PC)

College of Science & Engineering, James Cook University, Townsville, QLD, 4811, Australia. peter.junk@jcu.edu.au.
ORCID: 0000-0002-0683-8918

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Classifications MeSH

questionsmedicales.fr › Produits chimiques inorganiques › Éléments › Carbone › Selective carbon-phosphorus bond cleavage:...
questionsmedicales.fr › Produits chimiques inorganiques › Métaux › Terres rares › Lanthanides › Europium › Selective carbon-phosphorus bond cleavage:...
questionsmedicales.fr › Produits chimiques inorganiques › Métaux › Terres rares › Lanthanides › Selective carbon-phosphorus bond cleavage:...
questionsmedicales.fr › Produits chimiques inorganiques › Éléments › Phosphore › Selective carbon-phosphorus bond cleavage:...
questionsmedicales.fr › Produits chimiques inorganiques › Métaux › Terres rares › Lanthanides › Samarium › Selective carbon-phosphorus bond cleavage:...