Generation of a μ-1,2-hydroperoxo Fe
Journal
Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555
Informations de publication
Date de publication:
16 03 2022
16 03 2022
Historique:
received:
23
04
2021
accepted:
17
02
2022
entrez:
17
3
2022
pubmed:
18
3
2022
medline:
6
4
2022
Statut:
epublish
Résumé
μ-1,2-Peroxo-diferric intermediates (P) of non-heme diiron enzymes are proposed to convert upon protonation either to high-valent active species or to activated P' intermediates via hydroperoxo-diferric intermediates. Protonation of synthetic μ-1,2-peroxo model complexes occurred at the μ-oxo and not at the μ-1,2-peroxo bridge. Here we report a stable μ-1,2-peroxo complex {Fe
Identifiants
pubmed: 35296656
doi: 10.1038/s41467-022-28894-5
pii: 10.1038/s41467-022-28894-5
pmc: PMC8927127
doi:
Substances chimiques
Ferric Compounds
0
Ligands
0
Oxygen
S88TT14065
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
1376Informations de copyright
© 2022. The Author(s).
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