Oxetane Monomers Based On the Powerful Explosive LLM-116: Improved Performance, Insensitivity, and Thermostability.

LLM-116 energetic materials heterocycles nitration oxetane monomers

Journal

ChemPlusChem
ISSN: 2192-6506
Titre abrégé: Chempluschem
Pays: Germany
ID NLM: 101580948

Informations de publication

Date de publication:
03 2022
Historique:
revised: 17 02 2022
received: 14 02 2022
entrez: 24 3 2022
pubmed: 25 3 2022
medline: 6 5 2022
Statut: ppublish

Résumé

3-Bromomethyl-3-hydroxymethyloxetane represents an inexpensive and versatile precursor for the synthesis of 3,3-disubstituted oxetane derivatives. In the present work, its synthesis was improved and energetic oxetanes based on the explosive LLM-116 (4-amino-3,5-dinitro-1H-pyrazole) prepared. Reaching detonation velocities and pressures of up to 7335 ms

Identifiants

pubmed: 35324090
doi: 10.1002/cplu.202200049
doi:

Substances chimiques

Ethers, Cyclic 0
Explosive Agents 0
oxetane I279Q16FU6

Types de publication

Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202200049

Subventions

Organisme : Ludwig-Maximilians University of Munich (LMU)
Organisme : Office of Naval Research (ONR)
ID : ONR N00014-19-1-2078
Organisme : Strategic Environmental Research and Development Program (SERDP)
ID : WP19-1287
Organisme : Strategic Environmental Research and Development Program (SERDP)
ID : W912HQ19 C0033

Informations de copyright

© 2022 The Authors. ChemPlusChem published by Wiley-VCH GmbH.

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Auteurs

Max Born (M)

Department of Chemistry, Ludwig-Maximilians University of Munich, Butenandtstr. 5-13, 81377, Munich, Germany.

Konstantin Karaghiosoff (K)

Department of Chemistry, Ludwig-Maximilians University of Munich, Butenandtstr. 5-13, 81377, Munich, Germany.

Thomas M Klapötke (TM)

Department of Chemistry, Ludwig-Maximilians University of Munich, Butenandtstr. 5-13, 81377, Munich, Germany.

Michael Voggenreiter (M)

Department of Chemistry, Ludwig-Maximilians University of Munich, Butenandtstr. 5-13, 81377, Munich, Germany.

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