Metallation of sensitive fluoroarenes using a potassium TMP-zincate supported by a silyl(bis)amido ligand.
Journal
Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838
Informations de publication
Date de publication:
26 Apr 2022
26 Apr 2022
Historique:
pubmed:
12
4
2022
medline:
29
4
2022
entrez:
11
4
2022
Statut:
epublish
Résumé
Combining a bulky bis(amide) and a reactive one-coordinate TMP (2,2,6,6-tetramethylpiperidide) ligand, a new mixed K/Zn heteroleptic base has been developed for regioselective zincation of fluoroarenes. This special ligand set allows for trapping and structural authentication of the first intermediates of direct Zn-H exchange of fluoroarenes obtained
Identifiants
pubmed: 35403647
doi: 10.1039/d2cc00979j
pmc: PMC9040423
doi:
Substances chimiques
Amides
0
Ligands
0
Potassium
RWP5GA015D
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
5292-5295Références
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