Stretchable Redox-Active Semiconducting Polymers for High-Performance Organic Electrochemical Transistors.
organic electrochemical transistors
redox-active polymer semiconductors
stretchable electronics
Journal
Advanced materials (Deerfield Beach, Fla.)
ISSN: 1521-4095
Titre abrégé: Adv Mater
Pays: Germany
ID NLM: 9885358
Informations de publication
Date de publication:
Jun 2022
Jun 2022
Historique:
revised:
10
04
2022
received:
05
02
2022
pubmed:
22
4
2022
medline:
11
6
2022
entrez:
21
4
2022
Statut:
ppublish
Résumé
Organic electrochemical transistors (OECTs) represent an emerging device platform for next-generation bioelectronics owing to the uniquely high amplification and sensitivity to biological signals. For achieving seamless tissue-electronics interfaces for accurate signal acquisition, skin-like softness and stretchability are essential requirements, but they have not yet been imparted onto high-performance OECTs, largely due to the lack of stretchable redox-active semiconducting polymers. Here, a stretchable semiconductor is reported for OECT devices, namely poly(2-(3,3'-bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)-[2,2'-bithiophen]-5)yl thiophene) (p(g2T-T)), which gives exceptional stretchability over 200% strain and 5000 repeated stretching cycles, together with OECT performance on par with the state-of-the-art. Validated by systematic characterizations and comparisons of different polymers, the key design features of this polymer that enable the combination of high stretchability and high OECT performance are a nonlinear backbone architecture, a moderate side-chain density, and a sufficiently high molecular weight. Using this highly stretchable polymer semiconductor, an intrinsically stretchable OECT is fabricated with high normalized transconductance (≈223 S cm
Identifiants
pubmed: 35448913
doi: 10.1002/adma.202201178
doi:
Substances chimiques
Polymers
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
e2201178Subventions
Organisme : Office of Naval Research
ID : N00014-21-1-2266
Organisme : U.S. Department of Energy
Organisme : Office of Science
ID : DE-AC02-06CH11357
Organisme : Argonne National Laboratory
ID : DE-AC02-06CH11357
Organisme : U.S. Naval Research Laboratory
ID : N00014-21-1-2266
Informations de copyright
© 2022 The Authors. Advanced Materials published by Wiley-VCH GmbH.
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