The return of RET GateKeeper mutations? an in-silico exploratory analysis of potential resistance mechanisms to novel RET macrocyclic inhibitor TPX-0046.


Journal

Investigational new drugs
ISSN: 1573-0646
Titre abrégé: Invest New Drugs
Pays: United States
ID NLM: 8309330

Informations de publication

Date de publication:
10 2022
Historique:
received: 24 01 2022
accepted: 16 05 2022
pubmed: 26 5 2022
medline: 25 8 2022
entrez: 25 5 2022
Statut: ppublish

Résumé

TPX-0046 is designed to overcome resistance to FDA approved RET inhibitors Selpercatinib and Pralsetinib. Early prediction of resistance mechanisms to investigational drugs may facilitate subsequent drug and trial designs. This study aims to predict potential mutations inducing resistance to TPX-0046. We conducted an in-silico analysis of TPX-0046 macrocyclic structure and predicted the binding mode on RET. We used as reference literary examples of resistance mechanisms to other macrocyclic inhibitors (Lorlatinib on ALK/ROS1) to construct RET secondary resistance mutations. We conducted docking simulations to evaluate impact of mutations on TPX-0046 binding. TPX-0046 binding mode on RET appears to not be influenced by Solventfront G810X mutation presence. Bulky Gatekeeper V804X mutations affect predicted TPX-0046 binding mode. Mutations in Beta 7 strand region L881F and xDFG S891L impair TPX-0046 docking. Our findings suggest that development of second generation RET inhibitors focused mainly on Solventfront G810X mutations granting resistance to selective RET inhibitors Selpercatinib and Pralsetinib. If these findings are confirmed by identification of Gatekeeper V804X mutations in patients progressing to TPX-0046, explanation of acquired resistance and loss of benefit will be easier These findings might accelerate development of third generation RET inhibitors, as well as clinical trial design in precision oncology settings.

Identifiants

pubmed: 35612671
doi: 10.1007/s10637-022-01259-x
pii: 10.1007/s10637-022-01259-x
doi:

Substances chimiques

Protein Kinase Inhibitors 0
Proto-Oncogene Proteins 0
Anaplastic Lymphoma Kinase EC 2.7.10.1
Protein-Tyrosine Kinases EC 2.7.10.1
Proto-Oncogene Proteins c-ret EC 2.7.10.1
RET protein, human EC 2.7.10.1

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

1133-1136

Informations de copyright

© 2022. The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature.

Références

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Auteurs

Matteo Repetto (M)

Division of Early Drug Development for Innovative Therapies, European Institute of Oncology IRCCS, Milan, Italy.
Department of Oncology and Hemato-Oncology, University of Milan, Milan, Italy.

Edoardo Crimini (E)

Division of Early Drug Development for Innovative Therapies, European Institute of Oncology IRCCS, Milan, Italy.
Department of Oncology and Hemato-Oncology, University of Milan, Milan, Italy.

Liliana Ascione (L)

Division of Early Drug Development for Innovative Therapies, European Institute of Oncology IRCCS, Milan, Italy.
Department of Oncology and Hemato-Oncology, University of Milan, Milan, Italy.

Luca Boscolo Bielo (L)

Division of Early Drug Development for Innovative Therapies, European Institute of Oncology IRCCS, Milan, Italy.
Department of Oncology and Hemato-Oncology, University of Milan, Milan, Italy.

Carmen Belli (C)

Department of Oncology and Hemato-Oncology, University of Milan, Milan, Italy.

Giuseppe Curigliano (G)

Division of Early Drug Development for Innovative Therapies, European Institute of Oncology IRCCS, Milan, Italy. Giuseppe.curigliano@ieo.it.
Department of Oncology and Hemato-Oncology, University of Milan, Milan, Italy. Giuseppe.curigliano@ieo.it.

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