Controlled Modification of Axial Coordination for Transition-Metal Single-Atom Electrocatalyst.

axial coordination modification electrocatalysts electronic structures single-atom catalysts transition metals

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
21 Oct 2022
Historique:
received: 15 05 2022
pubmed: 17 6 2022
medline: 28 10 2022
entrez: 16 6 2022
Statut: ppublish

Résumé

Single-atom catalysts (SACs) have emerged as a new frontier in areas such as electrocatalysis, photocatalysis, and enzymatic catalysis. Aided by recent advances in the synthetic methodologies of nanomaterials, atomic characterization technologies, and theoretical calculation modeling, various SACs have been prepared for a variety of catalytic reactions. To meet the requirements of SACs with distinctive performance and appreciable selectivity, much research has been carried out to adjust the coordination configuration and electronic properties of SACs. This concept summarizes the latest advances in the experimental and computational efforts aimed at tuning the axial coordination of SACs. Series of atoms, functional groups or even macrocycles are oriented into the atomic metal center, and how this affects the electrocatalytic performance is also reviewed. Finally, this concept presents perspectives for the further precise design, preparation and in-situ detection of axially coordinated SACs.

Identifiants

pubmed: 35707987
doi: 10.1002/chem.202201471
doi:

Substances chimiques

Transition Elements 0
Metals 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202201471

Subventions

Organisme : the National Key Research and Development Program of China
ID : 2020YFB1506300
Organisme : National Natural Science Foundation of China
ID : Grant Nos. 21625102, 21971017, 21922502, 22075018, 51991344, 52025025, 52072400
Organisme : Beijing Engineering and Technology Research Center for Convergence Networks and Ubiquitous Services
Organisme : The Natural Science Foundation of Hainan Province
ID : 2019RC166
Organisme : Beijing Natural Science Foundation
ID : Z190010

Informations de copyright

© 2022 Wiley-VCH GmbH.

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Auteurs

Xiangjian Liu (X)

Key Laboratory of Cluster Science Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Advanced Technology Research Institute (Jinan), Advanced Research Institute of Multidisciplinary Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, No. 5, South Street, Zhongguancun, Haidian District, Beijing, 100081, P. R. China.

Yarong Liu (Y)

Key Laboratory of Cluster Science Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Advanced Technology Research Institute (Jinan), Advanced Research Institute of Multidisciplinary Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, No. 5, South Street, Zhongguancun, Haidian District, Beijing, 100081, P. R. China.

Wenxiu Yang (W)

Key Laboratory of Cluster Science Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Advanced Technology Research Institute (Jinan), Advanced Research Institute of Multidisciplinary Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, No. 5, South Street, Zhongguancun, Haidian District, Beijing, 100081, P. R. China.

Xiao Feng (X)

Key Laboratory of Cluster Science Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Advanced Technology Research Institute (Jinan), Advanced Research Institute of Multidisciplinary Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, No. 5, South Street, Zhongguancun, Haidian District, Beijing, 100081, P. R. China.

Bo Wang (B)

Key Laboratory of Cluster Science Ministry of Education, Beijing Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, Advanced Technology Research Institute (Jinan), Advanced Research Institute of Multidisciplinary Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, No. 5, South Street, Zhongguancun, Haidian District, Beijing, 100081, P. R. China.

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