Solvents drive self-assembly mechanisms and inherent properties of Kraft lignin nanoparticles (<50 nm).

Dimethyl Sulfoxide Lignin Nanoparticles Solvents
Elastic modulus Glass transition temperature Lignin nanoparticles Nucleation-growth mechanism Reinforcing filler Self-assembly Size-dependent properties Solvent shifting Specific surface area Spinodal decomposition mechanism

Journal

Journal of colloid and interface science
ISSN: 1095-7103
Titre abrégé: J Colloid Interface Sci
Pays: United States
ID NLM: 0043125

Informations de publication

Date de publication:
15 Nov 2022
Historique:
received: 31 01 2022
revised: 31 05 2022
accepted: 19 06 2022
pubmed: 6 7 2022
medline: 8 9 2022
entrez: 5 7 2022
Statut: ppublish

Résumé

Strikingly, Kraft lignin nanoparticles (KLNPs) can substitute polluting nanoparticles in diverse applications. An attractive method for synthesizing KLNPs is Solvent shifting. We hypothesized that by a detailed understanding of the solvent properties and influence of the process parameters, one could derive new fundamental and technical information about the lignin nanoparticle formation process. DMSO and THF were chosen best solvents based on the Hansen solubility parameter of lignin. The four synthesis parameters such as lignin concentration, (anti-solvent) water volume, temperature, and stirring speed were used to investigate the size, polydispersity index (PDI), morphology as well as the thermal, mechanical and optical properties of KLNPs KLNPs

Identifiants

DOI: 10.1016/j.jcis.2022.06.089 PMID: 35785603
pubmed: 35785603
pii: S0021-9797(22)01069-4
doi: 10.1016/j.jcis.2022.06.089
pii:
doi:

Substances chimiques

Solvents 0
Kraft lignin 8068-05-1
Lignin 9005-53-2
Dimethyl Sulfoxide YOW8V9698H

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

178-192

Informations de copyright

Copyright © 2022 The Authors. Published by Elsevier Inc. All rights reserved.

Déclaration de conflit d'intérêts

Declaration of Competing Interest Ahilan Manisekaran and Jean-Sébastien Thomann are inventors of the patent applications titled "Kraft Lignin Nanoparticles" (LU102105B1 and WO2022073858A1).

Auteurs

Ahilan Manisekaran (A)

Department of Materials Research and Technology, Luxembourg Institute of Science and Technology, L-4362 Esch-Sur-Alzette, Luxembourg; Department of Physics and Materials Science, University of Luxembourg, L-4365 Esch-sur-Alzette, Luxembourg.

Patrick Grysan (P)

Department of Materials Research and Technology, Luxembourg Institute of Science and Technology, L-4362 Esch-Sur-Alzette, Luxembourg.

Benoit Duez (B)

Goodyear Innovation Center Luxembourg, Avenue Gordon Smith, Colmar-Berg L-7750, Luxembourg.

Daniel F Schmidt (DF)

Department of Materials Research and Technology, Luxembourg Institute of Science and Technology, L-4362 Esch-Sur-Alzette, Luxembourg.

Damien Lenoble (D)

Department of Materials Research and Technology, Luxembourg Institute of Science and Technology, L-4362 Esch-Sur-Alzette, Luxembourg.

Jean-Sébastien Thomann (JS)

Department of Materials Research and Technology, Luxembourg Institute of Science and Technology, L-4362 Esch-Sur-Alzette, Luxembourg. Electronic address: jean-sebastien.thomann@list.lu.

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Classifications MeSH

questionsmedicales.fr › Composés chimiques organiques › Composés du soufre › Sulfoxydes › Diméthylsulfoxyde › Solvents drive self-assembly mechanisms and...
questionsmedicales.fr › Technologie, industrie et agriculture › Produits manufacturés › Matériaux biomédicaux et dentaires › Polymères › Biopolymères › Lignine › Solvents drive self-assembly mechanisms and...
questionsmedicales.fr › Technologie, industrie et agriculture › Produits manufacturés › Nanostructures › Nanoparticules › Solvents drive self-assembly mechanisms and...
questionsmedicales.fr › Actions chimiques et utilisations › Utilisations spécialisées de produits chimiques › Solvants › Solvents drive self-assembly mechanisms and...