Nickel-Catalyzed Enantioselective Reductive Alkyl-Carbamoylation of Internal Alkenes.

Alkenes / chemistry Catalysis Molecular Structure Nickel / chemistry Protein Carbamylation Stereoisomerism
Density Functional Theory Internal Alkenes Lactams Nickel Catalysis Vicinal Stereogenic Centers

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
05 09 2022
Historique:
received: 22 05 2022
pubmed: 13 7 2022
medline: 1 9 2022
entrez: 12 7 2022
Statut: ppublish

Résumé

Herein, we leverage the Ni-catalyzed enantioselective reductive dicarbofunctionalization of internal alkenes with alkyl iodides to enable the synthesis of chiral pyrrolidinones bearing vicinal stereogenic centers. The application of newly developed

Identifiants

DOI: 10.1002/anie.202207536 PMID: 35818326 PMC: PMC9427719
pubmed: 35818326
doi: 10.1002/anie.202207536
pmc: PMC9427719
mid: NIHMS1823642
doi:

Substances chimiques

Alkenes 0
Nickel 7OV03QG267

Types de publication

Journal Article Research Support, U.S. Gov't, Non-P.H.S. Research Support, N.I.H., Extramural Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202207536

Subventions

Organisme : NIGMS NIH HHS
ID : F32 GM134709
Pays : United States

Informations de copyright

© 2022 Wiley-VCH GmbH.

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Auteurs

Xianqing Wu (X)

Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai, 200237, China.

Aneta Turlik (A)

Department of Chemistry and Biochemistry, University of California, Los Angeles, CA, USA.

Baixue Luan (B)

Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai, 200237, China.

Feng He (F)

Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai, 200237, China.

Jingping Qu (J)

Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai, 200237, China.

K N Houk (KN)

Department of Chemistry and Biochemistry, University of California, Los Angeles, CA, USA.
ORCID: 0000-0002-8387-5261

Yifeng Chen (Y)

Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science & Technology, Shanghai, 200237, China.
ORCID: 0000-0003-3239-6209

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Classifications MeSH

questionsmedicales.fr › Composés chimiques organiques › Hydrocarbures › Hydrocarbures acycliques › Alcènes › Nickel-Catalyzed Enantioselective Reductive...
questionsmedicales.fr › Phénomènes chimiques › Catalyse › Nickel-Catalyzed Enantioselective Reductive...
questionsmedicales.fr › Phénomènes chimiques › Structure moléculaire › Nickel-Catalyzed Enantioselective Reductive...
questionsmedicales.fr › Produits chimiques inorganiques › Métaux › Métaux lourds › Nickel › Nickel-Catalyzed Enantioselective Reductive...
questionsmedicales.fr › Phénomènes physiologiques › Stress physiologique › Stress oxydatif › Carbamylation des protéines › Nickel-Catalyzed Enantioselective Reductive...
questionsmedicales.fr › Phénomènes chimiques › Phénomènes de chimie organique › Isomérie › Stéréoisomérie › Nickel-Catalyzed Enantioselective Reductive...