α-Thianthrenium Carbonyl Species: The Equivalent of an α-Carbonyl Carbocation.
Amino Acids
Carbocation
Carbonyl Compounds
Michael Acceptor
Umpolung
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
26 09 2022
26 09 2022
Historique:
received:
20
06
2022
pubmed:
28
7
2022
medline:
23
9
2022
entrez:
27
7
2022
Statut:
ppublish
Résumé
Here we report an α-thianthrenium carbonyl species, as the equivalent of an α-carbonyl carbocation, which is generated by the radical conjugate addition of a trifluoromethyl thianthrenium salt to Michael acceptors. The reactivity allows for the synthesis of C
Identifiants
pubmed: 35895980
doi: 10.1002/anie.202208978
pmc: PMC9804271
doi:
Substances chimiques
Acetonitriles
0
Amino Acids
0
Fluorides
Q80VPU408O
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202208978Informations de copyright
© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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