Periodate anions as a halogen bond donor: formation of anion⋯anion dimers and other adducts.
Journal
Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838
Informations de publication
Date de publication:
16 Aug 2022
16 Aug 2022
Historique:
pubmed:
30
7
2022
medline:
18
8
2022
entrez:
29
7
2022
Statut:
epublish
Résumé
Single crystal X-ray analyses show that iodine in pyridinium periodates acts as a halogen bond (HaB) donor forming short and almost linear contacts with neutral and anionic electron donors. A combination of QTAIM and NCIplot computational tools proves the attractive nature of these contacts.
Substances chimiques
Anions
0
Halogens
0
Polymers
0
Periodic Acid
10450-60-9
Iodine
9679TC07X4
metaperiodate
B45A1BUM4Q
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM