Alpha-Ketoglutarate or 5-HMF: Single Compounds Effectively Eliminate Leukemia Cells via Caspase-3 Apoptosis and Antioxidative Pathways.

5-hydroxy-methyl-furfural (5-HMF) alpha-ketoglutarate (aKG) caspase activity leukemia nitrated tyrosine peroxynitrite (ONOO−) proliferation reactive oxygen and nitrogen species (RONS)

Journal

International journal of molecular sciences
ISSN: 1422-0067
Titre abrégé: Int J Mol Sci
Pays: Switzerland
ID NLM: 101092791

Informations de publication

Date de publication:
12 Aug 2022
Historique:
received: 01 07 2022
revised: 31 07 2022
accepted: 08 08 2022
entrez: 26 8 2022
pubmed: 27 8 2022
medline: 30 8 2022
Statut: epublish

Résumé

We recently showed that a combined solution containing alpha-ketoglutarate (aKG) and 5-hydroxymethyl-furfural (5-HMF) has a solid antitumoral effect on the Jurkat cell line due to the fact of its antioxidative, caspase-3 and apoptosis activities, but no negative effect on human fibroblasts was obtained. The question arises how the single compounds, aKG and 5-HMF, affect peroxynitrite (ONOO The ONOO aKG showed a concentration-dependent reduction in ONOO Both substances showed high antioxidative potential in eliminating either peroxynitrite or nitration of tyrosine residues, which results in a better inhibition of cell growth and mitochondrial activity of 5-HMF compared to aKG. However, caspase-3-activated apoptosis measurements revealed that the combination of both substances synergistically is the most effective compared to single compounds.

Sections du résumé

BACKGROUND BACKGROUND
We recently showed that a combined solution containing alpha-ketoglutarate (aKG) and 5-hydroxymethyl-furfural (5-HMF) has a solid antitumoral effect on the Jurkat cell line due to the fact of its antioxidative, caspase-3 and apoptosis activities, but no negative effect on human fibroblasts was obtained. The question arises how the single compounds, aKG and 5-HMF, affect peroxynitrite (ONOO
METHODS METHODS
The ONOO
RESULTS RESULTS
aKG showed a concentration-dependent reduction in ONOO
CONCLUSION CONCLUSIONS
Both substances showed high antioxidative potential in eliminating either peroxynitrite or nitration of tyrosine residues, which results in a better inhibition of cell growth and mitochondrial activity of 5-HMF compared to aKG. However, caspase-3-activated apoptosis measurements revealed that the combination of both substances synergistically is the most effective compared to single compounds.

Identifiants

pubmed: 36012295
pii: ijms23169034
doi: 10.3390/ijms23169034
pmc: PMC9409265
pii:
doi:

Substances chimiques

Antioxidants 0
Ketoglutaric Acids 0
Peroxynitrous Acid 14691-52-2
Tyrosine 42HK56048U
Caspase 3 EC 3.4.22.-
Caspases EC 3.4.22.-

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Références

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Auteurs

Joachim Greilberger (J)

Division of Medical Chemistry, Otto Loewi Research, Medical University of Graz, 8010 Graz, Austria.
Institute of Scientific Laboratory Dr. Greilberger, Schwarzl Medical Center, 8053 Lassnitzhoehe, Austria.

Ralf Herwig (R)

Laboratories PD Dr. R. Herwig, 80337 Munich, Germany.
Heimerer-College, 10000 Pristina, Kosovo.

Mehtap Kacar (M)

Department of Physiology, Faculty of Medicine, Yeditepe University, Ataşehir, 34755 İstanbul, Turkey.
Department of Pathophysiology, Health Sciences Institute, Yeditepe University, Ataşehir, 34755 İstanbul, Turkey.

Naime Brajshori (N)

Heimerer-College, 10000 Pristina, Kosovo.

Georg Feigl (G)

Institute of Anatomy and Clinical Morphology, University of Witten/Herdecke, 58455 Witten, Germany.

Philipp Stiegler (P)

Division of Transplantation Surgery, Medical University of Graz, 8010 Graz, Austria.

Reinhold Wintersteiger (R)

Department of Pharmaceutical Chemistry, Institute of Pharmaceutical Sciences, University of Graz, 8010 Graz, Austria.

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Classifications MeSH