Room-Temperature-Observable Interconversion Between Si(IV) and Si(II) via Reversible Intramolecular Insertion Into an Aromatic C-C Bond.

Si ligands equilibrium silepins silylene small molecule activation

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
09 Dec 2022
Historique:
received: 26 07 2022
pubmed: 14 9 2022
medline: 14 9 2022
entrez: 13 9 2022
Statut: ppublish

Résumé

An easily isolable silacycloheptatriene (silepin) 1 b was synthesized from the reaction of a N-heterocyclic imino (IPrN) substituted tribromosilane IPrNSiBr

Identifiants

pubmed: 36098491
doi: 10.1002/chem.202202330
pmc: PMC10092829
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202202330

Informations de copyright

© 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.

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Auteurs

Teresa Eisner (T)

School of Natural Sciences, Department of Chemistry WACKER-Institute of Silicon Chemistry and Catalysis Research Centre Technical University of Munich, Lichtenbergstraße 4, 85748, Garching bei München, Germany.

Arseni Kostenko (A)

School of Natural Sciences, Department of Chemistry WACKER-Institute of Silicon Chemistry and Catalysis Research Centre Technical University of Munich, Lichtenbergstraße 4, 85748, Garching bei München, Germany.

Franziska Hanusch (F)

School of Natural Sciences, Department of Chemistry WACKER-Institute of Silicon Chemistry and Catalysis Research Centre Technical University of Munich, Lichtenbergstraße 4, 85748, Garching bei München, Germany.

Shigeyoshi Inoue (S)

School of Natural Sciences, Department of Chemistry WACKER-Institute of Silicon Chemistry and Catalysis Research Centre Technical University of Munich, Lichtenbergstraße 4, 85748, Garching bei München, Germany.

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