Nanoscale Synergetic Effects on Ag-TiO

hybrid structures photocatalysis reusability surface-enhanced Raman spectroscopy ultra-sensitivity

Journal

Small (Weinheim an der Bergstrasse, Germany)
ISSN: 1613-6829
Titre abrégé: Small
Pays: Germany
ID NLM: 101235338

Informations de publication

Date de publication:
12 2022
Historique:
revised: 26 08 2022
received: 22 06 2022
pubmed: 23 9 2022
medline: 20 12 2022
entrez: 22 9 2022
Statut: ppublish

Résumé

Here, a 4N-in-1 hybrid substrate concept (nanocolumnar structures, nanocrack network, nanoscale mixed oxide phases, and nanometallic structures) for ultra-sensitive and reliable photo-induced-enhanced Raman spectroscopy (PIERS), is proposed. The use of the 4N-in-1 hybrid substrate leads to an ≈50-fold enhancement over the normal surface-enhanced Raman spectroscopy, which is recorded as the highest PIERS enhancement to date. In addition to an improved Raman signal, the 4N-in-1 hybrid substrate provides a high detection sensitivity which may be attributed to the activation possibility at extremely low UV irradiation dosage and prolonged relaxation time (long measurement time). Moreover, the 4N-in-1 hybrid substrate exhibits a superior photocatalytic degradation performance of analytes, allowing its reuse at least 18 times without any loss of PIERS activity. The use of the 4N-in-1 concept can be adapted to biomedicine, forensic, and security fields easily.

Identifiants

pubmed: 36135727
doi: 10.1002/smll.202203861
doi:

Substances chimiques

titanium dioxide 15FIX9V2JP
Silver 3M4G523W1G
Titanium D1JT611TNE

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2203861

Informations de copyright

© 2022 The Authors. Small published by Wiley-VCH GmbH.

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Auteurs

Josiah Shondo (J)

Chair for Multicomponent Materials, Institute of Materials Science, Faculty of Engineering, Kiel University, Kaiserstr. 2, 24143, Kiel, Germany.

Salih Veziroglu (S)

Chair for Multicomponent Materials, Institute of Materials Science, Faculty of Engineering, Kiel University, Kaiserstr. 2, 24143, Kiel, Germany.
Kiel Nano, Surface and Interface Science KiNSIS, Kiel University, Christian Albrechts-Platz 4, 24118, Kiel, Germany.

Tim Tjardts (T)

Chair for Multicomponent Materials, Institute of Materials Science, Faculty of Engineering, Kiel University, Kaiserstr. 2, 24143, Kiel, Germany.

Tamim Bin Sarwar (TB)

Chair for Multicomponent Materials, Institute of Materials Science, Faculty of Engineering, Kiel University, Kaiserstr. 2, 24143, Kiel, Germany.

Yogendra Kumar Mishra (YK)

Mads Clausen Institute, NanoSYD, University of Southern Denmark, Alsion 2, Sønderborg, 6400, Denmark.

Franz Faupel (F)

Chair for Multicomponent Materials, Institute of Materials Science, Faculty of Engineering, Kiel University, Kaiserstr. 2, 24143, Kiel, Germany.
Kiel Nano, Surface and Interface Science KiNSIS, Kiel University, Christian Albrechts-Platz 4, 24118, Kiel, Germany.

Oral Cenk Aktas (OC)

Chair for Multicomponent Materials, Institute of Materials Science, Faculty of Engineering, Kiel University, Kaiserstr. 2, 24143, Kiel, Germany.
Additive Manufacturing Excellence Centre - URTEMM, Kahramankazan, Ankara, 06980, Turkey.

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