Binding of Glycans to the SARS CoV-2 Spike Protein, an Open Question: NMR Data on Binding Site Localization, Affinity, and Selectivity.


Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
20 Dec 2022
Historique:
received: 22 08 2022
pubmed: 27 9 2022
medline: 23 12 2022
entrez: 26 9 2022
Statut: ppublish

Résumé

We have used NMR experiments to explore the binding of selected glycans and glycomimetics to the SARS CoV-2 spike glycoprotein (S-protein) and to its receptor binding domain (RBD). STD NMR experiments confirm the binding of sialoglycans to the S-protein of the prototypic Wuhan strain virus and yield dissociation constants in the millimolar range. The absence of STD effects for sialoglycans in the presence of the Omicron/BA.1 S-protein reflects a loss of binding as a result of S-protein evolution. Likewise, no STD effects are observed for the deletion mutant Δ143-145 of the Wuhan S-protein, thus supporting localization of the binding site in the N-terminal domain (NTD). The glycomimetics Oseltamivir and Zanamivir bind weakly to the S-protein of both virus strains. Binding of blood group antigens to the Wuhan S-protein cannot be confirmed by STD NMR. Using

Identifiants

pubmed: 36161798
doi: 10.1002/chem.202202614
pmc: PMC9537997
doi:

Substances chimiques

spike protein, SARS-CoV-2 0
Spike Glycoprotein, Coronavirus 0
Polysaccharides 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202202614

Subventions

Organisme : Deutsche Forschungsgemeinschaft
ID : Pe494/12-1 and Pe494/12-2
Organisme : Deutsche Forschungsgemeinschaft
ID : EXC 2155 / Project No. 390874280
Organisme : Deutsche Forschungsgemeinschaft
ID : WBP Scholarship, Project No 494746248
Organisme : European Funds for Regional Development
ID : LPW E/1.1.2/857
Organisme : NaFoUniMedCovid19
ID : FKZ: 01KX2021

Informations de copyright

© 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.

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Auteurs

Thorben Maass (T)

Institute of Chemistry and Metabolomics, Center of Structural and Cell Biology in Medicine, University of Lübeck, Ratzeburger Allee 160, 23562, Lübeck, Germany.

George Ssebyatika (G)

Institute of Biochemistry, Center of Structural and Cell Biology in Medicine, University of Lübeck, Ratzeburger Allee 160, 23562, Lübeck, Germany.

Marlene Brückner (M)

Institute of Chemistry and Metabolomics, Center of Structural and Cell Biology in Medicine, University of Lübeck, Ratzeburger Allee 160, 23562, Lübeck, Germany.

Lea Breckwoldt (L)

Institute of Chemistry and Metabolomics, Center of Structural and Cell Biology in Medicine, University of Lübeck, Ratzeburger Allee 160, 23562, Lübeck, Germany.

Thomas Krey (T)

Institute of Biochemistry, Center of Structural and Cell Biology in Medicine, University of Lübeck, Ratzeburger Allee 160, 23562, Lübeck, Germany.
Centre for Structural Systems Biology (CSSB), Notkestraße 85, 22607, Hamburg, Germany.
German Center for Infection Research (DZIF) Partner Site Hamburg-Luebeck-Borstel-Riems, Ratzeburger Allee 160, 23562, Lübeck, Germany.
Cluster of Excellence RESIST (EXC 2155) and Institute of Virology, Hannover Medical School, Carl-Neuberg-Straße 1, 30625, Hannover, Germany.

Alvaro Mallagaray (A)

Institute of Chemistry and Metabolomics, Center of Structural and Cell Biology in Medicine, University of Lübeck, Ratzeburger Allee 160, 23562, Lübeck, Germany.

Thomas Peters (T)

Institute of Chemistry and Metabolomics, Center of Structural and Cell Biology in Medicine, University of Lübeck, Ratzeburger Allee 160, 23562, Lübeck, Germany.

Martin Frank (M)

Biognos AB, 40274, Göteborg, Sweden.

Robert Creutznacher (R)

Institute of Chemistry and Metabolomics, Center of Structural and Cell Biology in Medicine, University of Lübeck, Ratzeburger Allee 160, 23562, Lübeck, Germany.
Present address R.C.: Virology Section, Infectious Diseases and Immunology Division, Department of Biomolecular Health Sciences, Faculty of Veterinary Medicine, University of Utrecht, Yalelaan 1, 3584 CL, Utrecht (The, Netherlands.

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