Semirigid Ligands Enhance Different Coordination Behavior of Nd and Dy Relevant to Their Separation and Recovery in a Non-aqueous Environment.
Journal
Inorganic chemistry
ISSN: 1520-510X
Titre abrégé: Inorg Chem
Pays: United States
ID NLM: 0366543
Informations de publication
Date de publication:
10 Oct 2022
10 Oct 2022
Historique:
pubmed:
1
10
2022
medline:
12
10
2022
entrez:
30
9
2022
Statut:
ppublish
Résumé
Rare-earth elements are widely used in high-end technologies, the production of permanent magnets (PMs) being one of the sectors with the greatest current demand and likely greater future demand. The combination of Nd and Dy in NdFeB PMs enhances their magnetic properties but makes their recycling more challenging. Due to the similar chemical properties of Nd and Dy, their separation is expensive and currently limited to the small scale. It is therefore crucially important to devise efficient and selective methods that can recover and then reuse those critical metals. To address these issues, a series of heptadentate Trensal-based ligands were used for the complexation of Dy
Identifiants
pubmed: 36177719
doi: 10.1021/acs.inorgchem.2c02619
pmc: PMC9554911
doi:
Substances chimiques
Coordination Complexes
0
Ions
0
Ligands
0
Solvents
0
Acetone
1364PS73AF
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
16110-16121Références
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