Effect of Poly(Oxanorbonene)- and Poly(Methacrylate)-Based Polyzwitterionic Surface Coatings on Cell Adhesion and Gene Expression of Human Keratinocytes.


Journal

Macromolecular bioscience
ISSN: 1616-5195
Titre abrégé: Macromol Biosci
Pays: Germany
ID NLM: 101135941

Informations de publication

Date de publication:
11 2022
Historique:
revised: 21 09 2022
received: 04 06 2022
pubmed: 7 10 2022
medline: 16 11 2022
entrez: 6 10 2022
Statut: ppublish

Résumé

Polyzwitterions are generally known for their anti-adhesive properties, including resistance to protein and cell adhesion, and overall high bio-inertness. Yet there are a few polyzwitterions to which mammalian cells do adhere. To understand the structural features of this behavior, a panel of polyzwitterions with different functional groups and overall degrees of hydrophobicity is analyzed here, and their physical and biological properties are correlated to these structural differences. Cell adhesion is focused on, which is the basic requirement for cell viability, proliferation, and growth. With the here presented polyzwitterion panel, three different types of cell-surface interactions are observed: adhesion, slight attachment, and cell repellency. Using immunofluorescence methods, it is found that human keratinocytes (HaCaT) form focal adhesions on the cell-adhesive polyzwitterions, but not on the sample that has only slight cell attachment. Gene expression analysis indicates that HaCaT cells cultivated in the presence of a non-adhesive polyzwitterion have up-regulated inflammatory and apoptosis-related cell signaling pathways, while the gene expression of HaCaT cells grown on a cell-adhesive polyzwitterion does not differ from the gene expression of the growth control, and thus can be defined as fully cell-compatible.

Identifiants

pubmed: 36200655
doi: 10.1002/mabi.202200225
doi:

Substances chimiques

Methacrylates 0

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2200225

Informations de copyright

© 2022 The Authors. Macromolecular Bioscience published by Wiley-VCH GmbH.

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Auteurs

Alice Eickenscheidt (A)

Department of Microsystems Engineering (IMTEK), University of Freiburg, Georges-Köhler-Allee 103, 79110, Freiburg, Germany.
Freiburg Center for Interactive Materials and Bioinspired Technologies (FIT), University of Freiburg, Georges-Köhler-Allee 105, 79110, Freiburg, Germany.

Valentine Lavaux (V)

Department of Microsystems Engineering (IMTEK), University of Freiburg, Georges-Köhler-Allee 103, 79110, Freiburg, Germany.
Freiburg Center for Interactive Materials and Bioinspired Technologies (FIT), University of Freiburg, Georges-Köhler-Allee 105, 79110, Freiburg, Germany.

Stefan Paschke (S)

Department of Microsystems Engineering (IMTEK), University of Freiburg, Georges-Köhler-Allee 103, 79110, Freiburg, Germany.
Freiburg Center for Interactive Materials and Bioinspired Technologies (FIT), University of Freiburg, Georges-Köhler-Allee 105, 79110, Freiburg, Germany.

Alejandro Guajardo Martínez (AG)

Institut für Chemie, Universität Potsdam, Karl-Liebknecht Str. 25, 14476, Potsdam-Golm, Germany.

Eric Schönemann (E)

Institut für Chemie, Universität Potsdam, Karl-Liebknecht Str. 25, 14476, Potsdam-Golm, Germany.

André Laschewsky (A)

Institut für Chemie, Universität Potsdam, Karl-Liebknecht Str. 25, 14476, Potsdam-Golm, Germany.
Fraunhofer Institut für Angewandte Polymerforschung, 14476, Potsdam-Golm, Germany.

Karen Lienkamp (K)

Department of Materials Science, Saarland University, Campus, 66123, Saarbrücken, Germany.

Ori Staszewski (O)

Institute for Neuropathology, Medical Center of the University of Freiburg, Hugstetter Str. 55, 79106, Freiburg, Germany.

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