Porous material based on modified carbon and the effect of pore size distribution on the adsorption of methylene blue dye from an aqueous solution.
Chemical activation
Methylene blue
Pore hierarchy, Directed regulation of pores
Porous material
Porous structure
Journal
Environmental science and pollution research international
ISSN: 1614-7499
Titre abrégé: Environ Sci Pollut Res Int
Pays: Germany
ID NLM: 9441769
Informations de publication
Date de publication:
Feb 2023
Feb 2023
Historique:
received:
18
07
2022
accepted:
03
10
2022
pubmed:
28
10
2022
medline:
25
2
2023
entrez:
27
10
2022
Statut:
ppublish
Résumé
Carbon porous materials obtained through KOH activation of a furfural + hydroquinone + urotropine mixture were applied as adsorbent for the remediation of methylene blue (MB). The impact of porous structure with special attention to pore size distribution along with well-known pore volume and specific surface area on the remediation of MB was well investigated and elucidated. Findings obtained revealed that pore size distribution plays a crucial role in the liquid-phase adsorption of organic dyes like MB. By varying the synthesis mode parameters, in particular, the activating agent/precursor mass ratio, with the composition and initial components ratios remaining unchanged, samples with different pore size distribution were obtained. It was found that the material predominantly containing pores with an average equivalent diameter of ~ 3.5 nm appears to be the efficient MB adsorbent. The resulting highly porous carbon materials demonstrated high MB adsorption capacity (up to 2555 mg/g). Furthermore, to fully elucidate the adsorption mechanisms occurring on the obtained materials, a comprehensive mathematical processing of experimental data was performed out using the known kinetic and diffusion models (pseudo-first- and pseudo-second order, and intraparticle diffusion), as well as adsorption equilibrium isotherm models (Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich).It can be concluded that the porous carbon materials obtained and described in the present work are effective adsorbents for the removal of MB and may possess great potential for the treatment of dye-containing wastewater.
Identifiants
pubmed: 36301394
doi: 10.1007/s11356-022-23486-8
pii: 10.1007/s11356-022-23486-8
doi:
Substances chimiques
Carbon
7440-44-0
Methylene Blue
T42P99266K
Wastewater
0
Water Pollutants, Chemical
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
22617-22630Subventions
Organisme : Russian Science Foundation
ID : 22-13-20074
Informations de copyright
© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.
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