Electronic, steric and catalytic properties of N-heterocyclic carbene rhodium(I) complexes linked to (metallo)porphyrins.

Rhodium Heterocyclic Compounds Porphyrins Electronics

Journal

Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838

Informations de publication

Date de publication:
29 Nov 2022
Historique:
pubmed: 15 11 2022
medline: 1 12 2022
entrez: 14 11 2022
Statut: epublish

Résumé

Electronic and steric properties of NHC ligands functionalized with porphyrins were investigated. When porphyrins are used as NHC-wingtips, nickel(II) in the macrocyle significantly improves the catalytic activity of the neighbouring NHC-Rh(I) complex in the conjugate addition of phenylboronic acid to cyclohexen-2-one.

Identifiants

DOI: 10.1039/d2cc05547c PMID: 36373377
pubmed: 36373377
doi: 10.1039/d2cc05547c
doi:

Substances chimiques

Rhodium DMK383DSAC
carbene 2465-56-7
Heterocyclic Compounds 0
Porphyrins 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

13270-13273

Auteurs

Ludivine Poyac (L)

ICGM, Univ Montpellier, CNRS, ENSCM, Montpellier 34293, France. sebastien.richeter@umontpellier.fr.

Stefano Scoditti (S)

Department of Chemistry and Chemical Technologies, Univ of Calabria, Via P. Bucci, Rende 87036, Italy.
ORCID: 0000-0001-9384-703X

Xavier Dumail (X)

ICGM, Univ Montpellier, CNRS, ENSCM, Montpellier 34293, France. sebastien.richeter@umontpellier.fr.

Michel Granier (M)

ICGM, Univ Montpellier, CNRS, ENSCM, Montpellier 34293, France. sebastien.richeter@umontpellier.fr.

Sébastien Clément (S)

ICGM, Univ Montpellier, CNRS, ENSCM, Montpellier 34293, France. sebastien.richeter@umontpellier.fr.
ORCID: 0000-0002-8473-8197

Rafael Gramage-Doria (R)

Univ Rennes, CNRS, ISCR-UMR 6226, Rennes, F-35000, France.
ORCID: 0000-0002-0961-4530

Charles H Devillers (CH)

ICMUB UMR 6302, CNRS, Univ Bourgogne Franche-Comté, 9 avenue Alain Savary, Dijon 21078, France.
ORCID: 0000-0001-9078-7035

Sébastien Richeter (S)

ICGM, Univ Montpellier, CNRS, ENSCM, Montpellier 34293, France. sebastien.richeter@umontpellier.fr.
ORCID: 0000-0001-5284-0931

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Classifications MeSH

questionsmedicales.fr › Produits chimiques inorganiques › Métaux › Métaux lourds › Rhodium › Electronic, steric and catalytic properties of...
questionsmedicales.fr › Composés hétérocycliques › Electronic, steric and catalytic properties of...
questionsmedicales.fr › Facteurs biologiques › Pigments biologiques › Porphyrines › Electronic, steric and catalytic properties of...
questionsmedicales.fr › Disciplines des sciences naturelles › Physique › Électronique › Electronic, steric and catalytic properties of...