Recyclable Cu-Ag bimetallic nanocatalyst for radical scavenging, dyes removal and antimicrobial applications.

An ecofriendly and cost effective green method has been used for the synthesis of recyclable, high functional nanoparticles. Bimetallic nanoparticles (BmNPs), Cu-Ag, have been synthesized using beetroot extract as reducing and capping agent. Formation of BmNPs was initially confirmed by UV-visible analysis, having distinct peaks of Ag at 429 nm and Cu at 628 nm. FTIR analysis also confirmed the association of bioactive phytochemicals with Cu-Ag nanoparticles. Crystallinity and morphology of BmNPs was determined through X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), dynamic light scattering (DLS) and energy dispersion X-ray spectroscopy (EDAX). The size of spherical shape Cu-Ag BmNPs was found to be 75.58 nm and EDAX studies confirmed the percent elemental composition of Cu and Ag in synthesized nanocatalyst. Results of different analysis provided supported evidences regarding the formation of BmNPs. Catalytic potential of BmNPs was tested for the degradation of rhodamine B (Rh-B), methylene blue (MB) and methyl orange (MO) dyes. Cu-Ag BmNPs exhibited outstanding catalytic activity for the degradation of selected organic dyes and percent degradation was recorded more than 90% for each dye. In addition, antiradical property of BmNPs was tested employing DPPH

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Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.