Catalytic reduction of organic pollutants, antibacterial and antifungal activities of AgNPs@CuO nanoparticles-loaded mesoporous silica.


Journal

Environmental science and pollution research international
ISSN: 1614-7499
Titre abrégé: Environ Sci Pollut Res Int
Pays: Germany
ID NLM: 9441769

Informations de publication

Date de publication:
Mar 2023
Historique:
received: 08 09 2022
accepted: 15 11 2022
pubmed: 29 11 2022
medline: 11 3 2023
entrez: 28 11 2022
Statut: ppublish

Résumé

In this work, the mesoporous silica MCM-41 was prepared by a hydrothermal method and then modified using silver and copper. The obtained samples were used as antibacterial/antifungal agents and as catalysts for the reduction of the following dyes: Methylene Blue (MB), Congo Red (CR), Methyl Orange (MO), and Orange G (OG). Several parameters affecting the reduction of dyes were investigated and discussed such as the catalyst nature, the initial concentration of the dye, the dye nature, the selectivity of the catalyst in a binary system as well as the catalyst reuse. The catalysts were characterized using XRD, nitrogen sorption measurements, XRF, FTIR, XPS, SEM/EDS, and TEM. XRD, XPS, and TEM analysis clearly showed that the calcination of copper- and silver-modified silica leads to the formation of well-dispersed CuO and AgNPs having sizes between 5 and 10 nm. As determined by XRF analysis, the content of silver nanoparticles was higher compared to CuO in all samples. It has been shown that the dye reduction is influenced by the size and the content of nanoparticles as well as by their dispersions. The catalytic activity was shown to be the highest for the Ag-Cu-MCM(0.05) catalyst with a rate constant of 0.114, 0.102, 0.093, and 0.056 s

Identifiants

pubmed: 36441305
doi: 10.1007/s11356-022-24317-6
pii: 10.1007/s11356-022-24317-6
doi:

Substances chimiques

cupric oxide V1XJQ704R4
Copper 789U1901C5
Antifungal Agents 0
Silver 3M4G523W1G
Environmental Pollutants 0
Coloring Agents 0
Congo Red 3U05FHG59S
Silicon Dioxide 7631-86-9
Anti-Bacterial Agents 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

30855-30873

Informations de copyright

© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.

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Auteurs

Fatima Habeche (F)

Département de Génie Des Matériaux, Faculté de Chimie, Université Des Sciences Et de La Technologie Mohamed Boudiaf, BP 1505, El-Mnaouer, 31000, Oran, Algeria.

Bouhadjar Boukoussa (B)

Département de Génie Des Matériaux, Faculté de Chimie, Université Des Sciences Et de La Technologie Mohamed Boudiaf, BP 1505, El-Mnaouer, 31000, Oran, Algeria. bouhadjar.boukoussa@univ-usto.dz.
Laboratoire de Chimie Des Matériaux L.C.M, Université Oran1 Ahmed Ben Bella, BP 1524 El-Mnaouer, 31000, Oran, Algeria. bouhadjar.boukoussa@univ-usto.dz.

Ismail Issam (I)

Department of Chemical Engineering, Khalifa University of Science and Technology, P.O. Box 127788, Abu Dhabi, United Arab Emirates.

Adel Mokhtar (A)

Laboratoire de Chimie Des Matériaux L.C.M, Université Oran1 Ahmed Ben Bella, BP 1524 El-Mnaouer, 31000, Oran, Algeria.
Département Génie Des Procédés, Institut Des Sciences Et Technologies, Université Ahmed Zabana, 48000, Relizane, Algeria.

Xinnan Lu (X)

Department of Mechanical Engineering, Masdar Institute, Khalifa University of Science and Technology, P.O. Box 127788, Abu Dhabi, United Arab Emirates.

Jibran Iqbal (J)

College of Natural and Health Sciences, Zayed University, P.O. Box 144534, Abu Dhabi, United Arab Emirates.

Salih Hacini (S)

Laboratoire de Chimie Fine LCF, Université Oran1 Ahmed Ben Bella, BP‑1524, El‑Mnaouer, 31000, Oran, Algeria.

Mohammed Hachemaoui (M)

Laboratoire de Chimie Des Matériaux L.C.M, Université Oran1 Ahmed Ben Bella, BP 1524 El-Mnaouer, 31000, Oran, Algeria.
Département de Sciences de La Matière, Institut Des Sciences Et Technologies, Université Ahmed Zabana, 48000, Relizane, Algeria.

Abdelkader Bengueddach (A)

Laboratoire de Chimie Des Matériaux L.C.M, Université Oran1 Ahmed Ben Bella, BP 1524 El-Mnaouer, 31000, Oran, Algeria.

Rachida Hamacha (R)

Laboratoire de Chimie Des Matériaux L.C.M, Université Oran1 Ahmed Ben Bella, BP 1524 El-Mnaouer, 31000, Oran, Algeria.

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