An Amphiphilic Peptide Carrier for HCl Transport.

chloride transport ionophores peptides proton transport symporter

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
04 Aug 2023
Historique:
received: 30 03 2023
medline: 8 8 2023
pubmed: 23 5 2023
entrez: 23 5 2023
Statut: ppublish

Résumé

Single molecules that co-transport cations as well as anions across lipid membranes are few despite their high biological utility. The elegant yet simple lipidomimmetic peptide design herein enables efficient HCl transport without the use of any external additives for proton transport. The carboxylic acids in the dipeptide scaffold provide a handle to append two long hydrophobic tails and also provide a polar hydrophilic carboxylate group. The peptide central unit also provides NH sites for anion binding. Protonation of the carboxylate group coupled with the weak halide binding of the terminal NH group results in HCl transport with transport rates of H

Identifiants

pubmed: 37218621
doi: 10.1002/chem.202301020
doi:

Substances chimiques

Anions 0
Peptides 0
Lipids 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202301020

Subventions

Organisme : Science and Engineering Research Board
ID : EMR/2016/007672
Organisme : Science and Engineering Research Board
ID : CRG/2022/007764
Organisme : DST-Nanomission
ID : SR/NM/NS-1039/2015
Organisme : DST-FIST
ID : SR/FST/CS-II/2017/37

Informations de copyright

© 2023 Wiley-VCH GmbH.

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Auteurs

Sabnam Kar (S)

Department of Chemistry, Indian Institute of Technology Bombay, Mumbai, 400076, India.

Nandita Madhavan (N)

Department of Chemistry, Indian Institute of Technology Bombay, Mumbai, 400076, India.

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