Bioorthogonal Drug Release from Nanometric Micelles in Living Cells.


Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
01 Aug 2023
Historique:
received: 28 04 2023
medline: 2 8 2023
pubmed: 23 6 2023
entrez: 23 6 2023
Statut: ppublish

Résumé

We explored a bioorthogonal approach to release drugs from stimuli-responsive micelles inside tumor cells. The concept relies on sydnonimine-based micelles that undergo quantitative cleavage in presence of cyclooctynes, hence releasing their content within living cells. Four cleavable micelles were developed to allow massive burst release of Entinostat, a potent histone deacetylase inhibitor, following their internalization inside cancer cells. A comparative study on the influence of the bioorthogonal-mediated versus passive drug release from micelles was carried out. The results indicated that a fast release of the drug triggered a stronger antiproliferative activity on tumor cells compared to the passive diffusion of the drug from the micelles core. These finding may be of great interest for the development of new nanomedicines.

Identifiants

pubmed: 37350524
doi: 10.1002/chem.202301359
doi:

Substances chimiques

Micelles 0
Drug Carriers 0
Doxorubicin 80168379AG

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202301359

Subventions

Organisme : Agence Nationale de la Recherche
ID : ANR-19-CE06-0006-01

Informations de copyright

© 2023 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH.

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Auteurs

Léa Madegard (L)

CEA, INRAE, Département Médicaments et Technologies pour la Santé (DMTS), SCBM, Université Paris Saclay, 91191, Gif-sur-Yvette, France.

Melissa Girard (M)

Equipe Labellisée Ligue Contre le Cancer, UMR CNRS 7285 Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP), Université de Poitiers, 4 rue Michel-Brunet, TSA 51106, 86073, Poitiers cedex 9, France.

Benjamin Riss Yaw (BR)

Equipe Labellisée Ligue Contre le Cancer, UMR CNRS 7285 Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP), Université de Poitiers, 4 rue Michel-Brunet, TSA 51106, 86073, Poitiers cedex 9, France.

Karine Porte (K)

CEA, INRAE, Département Médicaments et Technologies pour la Santé (DMTS), SCBM, Université Paris Saclay, 91191, Gif-sur-Yvette, France.

Davide Audisio (D)

CEA, INRAE, Département Médicaments et Technologies pour la Santé (DMTS), SCBM, Université Paris Saclay, 91191, Gif-sur-Yvette, France.

Sébastien Papot (S)

Equipe Labellisée Ligue Contre le Cancer, UMR CNRS 7285 Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP), Université de Poitiers, 4 rue Michel-Brunet, TSA 51106, 86073, Poitiers cedex 9, France.

Frédéric Taran (F)

CEA, INRAE, Département Médicaments et Technologies pour la Santé (DMTS), SCBM, Université Paris Saclay, 91191, Gif-sur-Yvette, France.

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Classifications MeSH