Chalcogen-bridged coordination polymer for the photocatalytic activation of aryl halides.
Journal
Nature communications
ISSN: 2041-1723
Titre abrégé: Nat Commun
Pays: England
ID NLM: 101528555
Informations de publication
Date de publication:
06 Jul 2023
06 Jul 2023
Historique:
received:
12
01
2022
accepted:
16
06
2023
medline:
10
7
2023
pubmed:
7
7
2023
entrez:
6
7
2023
Statut:
epublish
Résumé
The ability to deliver electrons is vital for dye-based photocatalysts. Conventionally, the aromatic stacking-based charge-transfer complex increases photogenerated electron accessibility but decreases the energy of excited-state dyes. To circumvent this dilemma, here we show a strategy by tuning the stacking mode of dyes. By decorating naphthalene diimide with S-bearing branches, the S···S contact-linked naphthalene diimide string is created in coordination polymer, thereby enhancing electron mobility while simultaneously preserving competent excited-state reducing power. This benefit, along with in situ assembly between naphthalene diimide strings and exogenous reagent/reactant, improves the accessibility of short-lived excited states during consecutive photon excitation, resulting in greater efficiency in photoinduced electron-transfer activation of inert bonds in comparison to other coordination polymers with different dye-stacking modes. This heterogeneous approach is successfully applied in the photoreduction of inert aryl halides and the successive formation of C
Identifiants
pubmed: 37414824
doi: 10.1038/s41467-023-39540-z
pii: 10.1038/s41467-023-39540-z
pmc: PMC10326065
doi:
Substances chimiques
naphthalenediimide
22291-04-9
Polymers
0
Naphthalenes
0
Inorganic Chemicals
0
Chalcogens
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
4002Subventions
Organisme : National Natural Science Foundation of China (National Science Foundation of China)
ID : 21820102001
Organisme : National Natural Science Foundation of China (National Science Foundation of China)
ID : 21890381
Organisme : National Natural Science Foundation of China (National Science Foundation of China)
ID : 21231003
Organisme : National Natural Science Foundation of China (National Science Foundation of China)
ID : 21901033
Organisme : National Natural Science Foundation of China (National Science Foundation of China)
ID : 21971031
Informations de copyright
© 2023. The Author(s).
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