Light-Modulated Morphological Transformation of Spiropyran Derivative from Nanosphere to Nanorod.

morphological transformation photoswitchable morphology self-assembly spiropyran

Journal

Macromolecular rapid communications
ISSN: 1521-3927
Titre abrégé: Macromol Rapid Commun
Pays: Germany
ID NLM: 9888239

Informations de publication

Date de publication:
Nov 2023
Historique:
revised: 05 08 2023
received: 20 06 2023
medline: 6 11 2023
pubmed: 11 8 2023
entrez: 11 8 2023
Statut: ppublish

Résumé

The construction of tunable morphological systems has important implications for understanding the mechanism of molecular self-assembly. In this study, a spiropyran derivative M1 is reported with light-responsive assembly morphology, which can be tuned from nanosphere to nanorod by ultraviolet light irradiation. The absorption spectra show that M1 molecules are transformed from closed-ring (SP) isomers into open-ring (MC) isomers and start to form H-aggregates with increasing irradiation time. Density functional theory calculations indicate that MC-MC isomers possess stronger binding energy than SP-SP isomers. The MC isomers may thus facilitate the dissociation of the SP-SP aggregates and promote the change of self-assembled morphology with the aid of stronger π-π stackings and dipole-dipole interactions. The research gives an effective method for modulating the morphology of assemblies, with great potential for applications in smart materials.

Identifiants

pubmed: 37566799
doi: 10.1002/marc.202300360
doi:

Substances chimiques

spiropyran 0
Benzopyrans 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e2300360

Subventions

Organisme : Fundamental Research Funds for the Central Universities
ID : FRF-TP-22-003A1
Organisme : National Natural Science Foundation of China
ID : 52103049
Organisme : National Natural Science Foundation of China
ID : 22005021
Organisme : National Natural Science Foundation of China
ID : 51373025
Organisme : China Postdoctoral Science Foundation
ID : 2023M730311
Organisme : Open Research Fund of State Key Laboratory of Biobased Fiber Manufacturing Technology
ID : SKL202311
Organisme : Program for New Century Excellent Talents in University
ID : NCET-11-0582

Informations de copyright

© 2023 Wiley-VCH GmbH.

Références

P. A. Korevaar, S. J. George, A. J. Markvoort, M. M. J. Smulders, P. A. J. Hilbers, A. P. H. J. Schenning, T. F. A. De Greef, E. W. Meijer, Nature 2012, 481, 492.
a) Q. Zhang, L. Yue, R. Yan, D.-J. Liaw, J. Shi, Z. Li, C. Liang, Y. Cheng, Z. Ge, Y. Zhang, Macromol. Rapid Commun. 44, 2023, 2300092;
b) L. Florea, S. Scarmagnani, F. Benito-Lopez, D. Diamond, Chem. Commun. 2014, 50, 924.
N. L. Mutter, J. Volaric, W. Szymanski, B. L. Feringa, G. Maglia, J. Am. Chem. Soc. 2019, 141, 14356.
T. G. Barclay, K. Constantopoulos, J. Matisons, Chem. Rev. 2014, 114, 10217.
a) B. R. Heiner, A. M. Pittsford, S. A. Kandel, Chem. Commun. 2023, 59, 170;
b) B. Shi, D. Shen, W. Li, G. Wang, Macromol. Rapid Commun. 2022, 43, 2200071.
S. Son, E. Shin, B.-S. Kim, Biomacromolecules 2014, 15, 628.
M. Villa, G. Bergamini, P. Ceroni, M. Baroncini, Chem. Commun. 2019, 55, 11860.
H. Wang, C. N. Zhu, H. Zeng, X. Ji, T. Xie, X. Yan, Z. L. Wu, F. Huang, Adv. Mater. 2019, 31, 1807328.
a) A. Korpi, P. Skumial, M. A. Kostiainen, Macromol. Rapid Commun. 2019, 40, 1900308;
b) C. Huang, L. Wen, H. Liu, Y. Li, X. Liu, M. Yuan, J. Zhai, L. Jiang, D. Zhu, Adv. Mater. 2009, 21, 1721.
a) X. Zheng, Y. Jia, A. Chen, Nat. Commun. 2021, 12, 4875;
b) J. Zhang, S. You, S. Yan, K. Müllen, W. Yang, M. Yin, Chem. Commun. 2014, 50, 7511;
c) S. Zhou, M. Zeng, Y. Liu, X. Sui, J. Yuan, Macromol. Rapid Commun. 2022, 43, 2200010.
S. Mo, Q. Meng, S. Wan, Z. Su, H. Yan, B. Z. Tang, M. Yin, Adv. Funct. Mater. 27, 2017, 1701210.
J. He, Y. Yang, Y. Li, Z. He, Y. Chen, Z. Wang, H. Zhao, G. Jiang, Cell Rep Phys Sci 2021, 2, 100643.
J. Wang, B. Yang, M. Yu, H. Yu, ACS Appl. Mater. Interfaces 2022, 14, 15632.
K. Müller, J. Helfferich, F. Zhao, R. Verma, A. B. Kanj, V. Meded, D. Bléger, W. Wenzel, L. Heinke, Adv. Mater. 2018, 30, 1706551.
a) H. Yuan, H. Chong, B. Wang, C. Zhu, L. Liu, Q. Yang, F. Lv, S. Wang, J. Am. Chem. Soc. 2012, 134, 13184;
b) P. Li, Q. Yao, B. Lü, G. Ma, M. Yin, Macromol. Rapid Commun. 2018, 39, 1800133;
c) Y.-Y. Xiao, Z.-C. Jiang, J.-B. Hou, Y. Zhao, Nat. Commun. 2021, 12, 264;
d) H. Jiang, Y. Jiang, J. Han, L.i Zhang, M. Liu, Angew. Chem., Int. Ed. 2019, 58, 785.
a) B. Zhang, Y. Feng, W. Feng, Nano-Micro Lett. 2022, 14, 138;
b) M.-M. Russew, S. Hecht, Adv. Mater. 2010, 22, 3348.
a) F. Sun, D. Wang, J. Mater. Chem. C 2022, 10, 13700;
b) Z. Li, M. Tang, C. Jiang, R. Bai, W. Bai, Macromol. Rapid Commun. 2018, 39, 1700880.
P. Naumov, S. Chizhik, M. K. Panda, N. K. Nath, E. Boldyreva, Chem. Rev. 2015, 115, 12440.
a) R. Klajn, Chem. Soc. Rev. 2014, 43, 148;
b) C.-Q. Huang, Y. Wang, C.-Y. Hong, C.-Y. Pan, Macromol. Rapid Commun. 2011, 32, 1174.
J. Kim, H. Yun, Y. J. Lee, J. Lee, S.-H. Kim, K. H. Ku, B. J. Kim, J. Am. Chem. Soc. 2021, 143, 13333.
S. Chen, F. Jiang, Z. Cao, G. Wang, Z.-M. Dang, Chem. Commun. 2015, 51, 12633.
D. Wang, T. Zhang, B.o Wu, C. Ye, Z. Wei, Z. Cao, G. Wang, Macromolecules 2019, 52, 7130.
X. Zhou, Y. Duan, S. Yan, Z. Liu, C. Zhang, L. Yao, G. Cui, Chem. Commun. 2011, 47, 6876.
Y.i Wang, X. Tan, Y.u-M.o Zhang, S. Zhu, I. Zhang, B. Yu, K. Wang, B. Yang, M. Li, B.o Zou, S. X.-A. Zhang, J. Am. Chem. Soc. 2015, 137, 931.
Z. Wu, K. Pan, S. Mo, B. Wang, X. Zhao, M. Yin, ACS Appl. Mater. Interfaces 2018, 10, 30879.
Q. Qi, C. Li, X. Liu, S. Jiang, Z. Xu, R. Lee, M. Zhu, B. Xu, W. Tian, J. Am. Chem. Soc. 2017, 139, 16036.
R. Yang, Y. Jiao, B. Wang, B. Xu, W. Tian, J. Phys. Chem. Lett. 2021, 12, 1290.
E. Goldburt, F. Shvartsman, S. Fishman, V. Krongauz, Macromolecules 1984, 17, 1225.
I. Cabrera, V. Krongauz, Macromolecules 1987, 20, 2713.
I. Cabrera, F. Shvartsman, O. Veinberg, V. Krongauz, Science 1984, 226, 341.
E. Goldburt, V. Krongauz, Macromolecules 1986, 19, 246.
T. Lu, F. Chen, J. Comput. Chem. 2012, 33, 580.
Z. Wu, Q. Wang, P. Li, B. Fang, M. Yin, J. Mater. Chem. C 2021, 9, 6290.
Y. Zhang, M. Ng, E. Y.-H. Hong, A. K.-W. Chan, N. M.-W. Wu, M. H.-Y. Chan, L. Wu, V. W.-W. Yam, J. Mater. Chem. C 2020, 8, 13676.
J. Yang, Z. Xu, J. Wang, L. Gai, X. Ji, H. Jiang, L. Liu, Adv. Funct. Mater. 2021, 31, 2009438.
H. Park, H. S. Kim, Y. M. Jung, J. Phys. Chem. B 2011, 115, 1743.
H. Ren, S. Li, B.o Wang, Y. Zhang, T. Wang, Q. Lv, X. Zhang, L. Wang, X. Han, F. Jin, C. Bao, P. Yan, N. Zhang, D. Wang, T. Cheng, H. Liu, S. Dou, Adv Mater 2023, 35, 2208237.

Auteurs

Zhen Wu (Z)

School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, 100083, China.

Jiewen Ma (J)

School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, 100083, China.

Ruoyu Xu (R)

School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, 100083, China.

Shijie Zhong (S)

School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, 100083, China.

Xin Zhang (X)

School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, 100083, China.

Min Gong (M)

School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing, 100083, China.

Guojie Wang (G)

School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, 100083, China.

Articles similaires

Ultraviolet Rays Disinfection Ultrasonography Surface Properties Humans
Humans Keratoconus Male Cross-Linking Reagents Female
Humans Mesenchymal Stem Cells Extracellular Vesicles Skin Aging Tissue Inhibitor of Metalloproteinase-1
Caenorhabditis elegans Caenorhabditis elegans Proteins Humans Animals Caspases

Classifications MeSH